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Redox Reactions Test - 11

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Redox Reactions Test - 11
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  • Question 1
    1 / -0

    When a sulphur atom becomes a sulphide ion

    Solution

    \(S + 2e^- \rightarrow S^{2-}\)

  • Question 2
    1 / -0

    In the course of a chemical reaction an oxidant

    Solution

    Any substance which is capable of oxidising other substances and is capable of accepting/gaining electron during oxidation is called oxidising agent or oxidant.

  • Question 3
    1 / -0

    When sodium metal is dissolved in liquid ammonia, blue colour solution is formed. The blue colour is due to

    Solution

    When sodium metal is dissolved in liquid ammonia to form coloured solution. Dilute solutions are bright blue in colour due to the presence of solvated electrons.

    \(Na + (x + y)NH_3\) → \([Na(NH_3)x]^+ + [e(NH_3)y]^-\)

                                                                  Blue Colour

  • Question 4
    1 / -0

    In the reaction \(C_2O^{2-}_4 + MnO^-_4 + H^+\) → \(Mn^{2+} + CO_2 + H_2O\) the reluctant is

    Solution

    \(C_2O_4^{2-} + MnO_4^- + H^+\) → \(Mn^{2+} + CO_2 + H_2O\)

    In this reaction \(C_2O^{2-}_4\) act as a reducing agent.

  • Question 5
    1 / -0

    Which of the following is the most powerful oxidizing agent?

    Solution

    Fluorine is a most powerful oxidizing agent because it consists of \(E_o\) = +2.5 volt.

  • Question 6
    1 / -0

    The strongest reducing agent is

    Solution

    Hydrogen sulphide (\(H_2S\)) acts as strong reducing agent as it decomposes by evolving hydrogen.

  • Question 7
    1 / -0

    If 1.2 g of metal displaces 1.12 litre hydrogen at normal temperature and pressure, equivalent weight of metal would be

    Solution

    1.12 ltr \(H_2\) = 1.2g;

    \(\therefore\) 22.4 ltr \(H_2\) = 24g

  • Question 8
    1 / -0

    Prevention of corrosion of iron by zinc coating is called

    Solution

    Prevention of corrosion of iron by zinc coating is called Galvanization.

  • Question 9
    1 / -0

    The compound which could not act both as oxidising as well as reducing agent is

    Solution

    \(Al_2O_3\) could not act as a oxidising and reducing agent.

  • Question 10
    1 / -0

    \(M^{+3}\) ion loses \(3e^-\). Its oxidation number will be

    Solution

    2 x No. of \(e^-\) losses = Oxidation no.

    \(2 \times 3e^- = +6\)

  • Question 11
    1 / -0

    In which of the following compounds is the oxidation number of iodine is fractional

    Solution

    3x = -1

    x = \(- \frac{1}{3}\)

  • Question 12
    1 / -0

    The number of moles of \(KMnO_4\) reduced by one mole of KI in alkaline medium is

    Solution

    In alkaline medium

    \(2KMnO_4 + KI + H_2O\) → \(2MnO_2 + 2KOH + KIO_3\)

  • Question 13
    1 / -0

    One mole of \(N_2H_4\) loses 10 moles of electrons to form a new compound, y. Assuming that all nitrogen appears in the new compound, what is the oxidation state of nitrogen in y (There is no change in the oxidation state of hydrogen)

    Solution

    \(\overset{-4}{N_2}\overset{+4}{H_4}\) \(\underset{N}{\stackrel{loss\;of\;10e^-}{\longrightarrow}}\) \(\overset{+6}{N_2}\) 

    O.N. of N changes from -2 to +3

    1 mole of hydrazine contains 2 moles of N and loses 10 moles of electrons. Hence, 1 N atom will lose 5 electrons. Hence, its oxidation number will increase by 5. Hence, the oxidation number of N in compound A will be −2+5=+3

  • Question 14
    1 / -0

    The equivalent mass of oxidising agent in the following reaction is \(SO_2 + 2H_2S\) → \(3S + 2H_2O\)

    Solution

    \(SO_2\) is an oxidising agent \(4e^- + SO_2 \rightarrow S\)

    Equivalent of \(SO_2\)

    \(\frac{64}{4}\)

    = 16

  • Question 15
    1 / -0

    When \(SO_2\) is passed through acidified solution of potassium dichromate, then chromium sulphate is formed. The change in valency of chromium is

    Solution

    \(K_2Cr_2O_7 + 3SO_2 + 4H_2SO_4\) → \(K_2SO_4 + Cr_2(SO_4)_3\) \(+ 3SO_3 + 4H_2O\)

  • Question 16
    1 / -0

    Oxidation involves

    Solution

    It is the process in which electrons are lost (de-electronation).

  • Question 17
    1 / -0

    The conversion of sugar \(\mathrm {C_{12}H_{22}O_{11}}\)→ \(\mathrm {CO_2}\) is

    Solution

    In this reaction oxidation occurs.

  • Question 18
    1 / -0

    Which of the following is Redox Reaction?

    Solution

    \(2\overset{0}{N_2} + \overset{0}{O_2} \rightarrow 2\overset{+2}{N} \overset{-2}{O}\)

    Here O.N. of N increases from O in \(N_2\) to +2 in \(NO_2\) and that of decreased from O in \(O_2\) to -2 in O; therefore, it is a Redox reaction.

  • Question 19
    1 / -0

    When iron or zinc is added to \(CuSO_4\) solution, copper is precipitated. It is due to 

    Solution

    \(\overset{0}{Zn} + \overset{+2}{Cu}SO_4 \rightarrow\) \(ZnSO_4 + \overset{0}{Cu}\)

    In this reaction \(Cu^{2+}\) changes in \(\overset{o}{Cu}\), hence it is called as reduction reaction.

  • Question 20
    1 / -0

    Which halide is not oxidised by \(MnO_2\)

    Solution

    Fluorine has highest \(E^o\) value and more reactive than \(MnO_2\).

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