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Redox Reactions Test - 18

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Redox Reactions Test - 18
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  • Question 1
    1 / -0
    Which reaction involves neither oxidation nor reduction?
    Solution

    Hint: If a species releases an electron, it is called oxidation and if a species accepts an electron, it is called reduction.

    Step 1: Option A

    $${CrO_4}^{2-}\rightarrow {Cr_2{O_7}^{2-}}$$

    Here oxidation number of $$Cr$$ in $${CrO_4}^{2-}$$ is-

    $$x+{(4\times{-2})}=-2$$, where $$x$$ is the oxidation number of $$Cr$$.

    $$x=+6$$.

    Oxidation number of $$Cr$$ in $${Cr_2O_7}^{2-}$$ is-

    $$2x-14=-2$$

    $$x=+6$$

    So, there is no change in oxidation number. It does not undergo an oxidation or reduction reaction.

    Step 2: Option B

    $$Cr\rightarrow CrCl_3$$

    Oxidation number of $$Cr$$ is $$0$$ and oxidation number of $$Cr$$ in $$CrCl_3$$ is

    $$x-3=0$$, where $$x$$ is the oxidation number of $$Cr$$.

    $$x=+3$$

    Here $$Cr$$ releases three electrons to get converted to $$Cr^{+3}$$ and undergoes oxidation.

    Step 3: Option C

    $$Na\rightarrow Na^+$$

    Here $$Na$$ converted to $$Na^+$$ by releasing an electron and undergoes oxidation.

    Step 4: Option C

    $${S_2O_6}^{2-}\rightarrow {S_4O_6}^{2-}$$

    Oxidation number of $$S$$ in $${S_2O_6}^{2-}$$ is-

    $$2y-12=-2$$ , where $$y$$ is the oxidation number of $$S$$.

    $$y=+5$$

    Oxidation number of $${S_4O_6}^{2-}$$ is-

    $$4y-12=-2$$

    $$y=2.5$$

    So, here oxidation number decreases that means $$S$$ accepts electrons and undergoes reduction reaction.

    Final Step: Correct option is $$(A)$$.

  • Question 2
    1 / -0
    The oxidation states of sulphur in the anions, $$SO_{3}^{2-}$$, $$S_{2}O_{4}^{2-}$$ and $$S_{2}O_{6}^{2-}$$ follow the order :
    Solution
    Sulphur in $$SO_{3}^{-2},  S_{2}O_{4}^{-2},$$ and $$ S_{2}O_{6}^{-2}$$ has $$+4$$, $$+3$$ and $$+5$$ oxidation state respectively.
    Hence, the order is $$S_{2}O_{4}^{2-}$$<$$SO_{3}^{2-}$$<$$S_{2}O_{6}^{2-}$$.
  • Question 3
    1 / -0
    The oxidation state of the most electronegative atom in each of the product in the following reaction is
    $$H_{2}+O_{2}\rightarrow H_{2}O_{2}+H_{2}O$$
    Solution
    In hydrogen peroxide, the oxidation number of O is $$-1$$ as it is a peroxide (O-O) while in water it is $$-2$$ as it is an oxide (O$$^{2-}$$).
  • Question 4
    1 / -0
    Which of the following is a redox reaction?
    Solution
     $$Zn^{0}+2\mathrm{A}g^{+1}CN\rightarrow 2\mathrm{A}g^{0}+Zn^{+2}(CN)_{2}$$

    Oxidation of Zn while reduction of Ag occurs. 

    Hence, it is a redox reaction.
  • Question 5
    1 / -0
    When ammonium nitrate is gently heated, an oxide of nitrogen is formed. What is the oxidation state of nitrogen in this oxide?
    Solution
    When ammonium nitrate is gently heated, dinitrogen monoxide $$N_2O$$ is obtained.
    Let $$x$$ be the oxidation state of $$N$$ in $$N_2O$$.
    The oxidation state of oxygen is $$-2$$.
    The sum of the oxidation states for neutral molecule is $$0$$.
    Hence, $$2x+(-2)=0$$ or, $$x=+1$$.
    Therefore, the oxidation state of $$N$$ is $$+1$$.
  • Question 6
    1 / -0
    Iron shows least oxidation state in which of the following?
    Solution
    The oxidation states of iron in $$K_4[Fe(CN)_6], \ K_3[Fe(CN)_6], \ FeSO_4(NH_4)_2SO_4(6H_2O) \ and \ Fe_2(CO)_9$$ are $$+2, \:+3,\: +2$$ and $$0 $$ respectively.
    Hence, the least oxidation state of Fe is in $$Fe_2(CO)_9$$.
  • Question 7
    1 / -0
    In which one of the following compounds does oxygen have an oxidation number of $$+2$$?
    Solution
    Flourine is more electronegative than oxygen which in turn is more electronegative than Cl and Na. 
    The oxidation number of oxygen in $$F_2O,  Cl_2O,  Na_2O_2$$ and $$Na_2O$$ are $$+2, \:-2,\: -1$$ and $$-2$$ respectively.
  • Question 8
    1 / -0
    The oxidation number of $$Mn$$ in potassium permanganate is :
    Solution
    Let $$x$$ be the oxidation number of manganese in potassium permanganate. ($$KMnO_4$$)

    The oxidation numbers of potassium and oxygen are $$+1$$ and $$-2$$ respectively. 

    The sum of the oxidation numbers in a neutral molecule is zero.

    Hence, $$1+x+4(-2)=0$$ or, $$x=+7$$.
  • Question 9
    1 / -0
    In which of the following compounds, is the oxidation number of sulphur is the least?
    Solution
    The oxidation number of sulphur in $$SO_2, \: SO_3,\:  Na_2SO_4$$ and $$H_2SO_4$$ are $$+4,\: +6,\: +2.5$$ and $$+6$$ respectively. Hence, it is least in $$Na_2SO_4$$.
  • Question 10
    1 / -0
    Which of the following does not involve the change of valency?
    Solution
    The reaction between sodium peroxide and sulphuric acid to obtain sodium sulphate and hydrogen peroxide is a double displacement reaction in which the cations switch positions. Hence, there is no change in valency in this reaction.
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