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Redox Reactions Test - 38

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Redox Reactions Test - 38
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  • Question 1
    1 / -0
    The sum of oxidation number of nitrogen in $$NH_4NO_3$$ is:
    Solution
    Given $$NH_4NO_3$$ in the ionic state is present in the form of $$NH_4^++{NO_3}^-$$.

    $$\Rightarrow x+4=+1$$                           $$\Rightarrow x-6=-1$$
    $$\Rightarrow x= -3$$                                  $$\Rightarrow x=+5$$

    Sum of two oxidation states of $$N$$ gives $$+2$$ .
  • Question 2
    1 / -0
    The oxidation number of cobalt in $$K[Co(CO)_4]$$ is:
    Solution
    The oxidation number of colbalt in $$K[Co(CO)_4]$$ is:

    $$+1+x+0\times 4=0$$

    $$\therefore x=-1$$.

    Hence, option $$A$$ is correct.
  • Question 3
    1 / -0
    Oxalic acid dihydrate, $$H_{2}C_{2}O_{4}\cdot 2H_{2}O(s)$$ is often used as a primary reagent to standardise sodium hydroxide solution. Which of these facts are reasons to choose this substance as a primary standard?
    I. It is diprotic.
    II. It is a stable compound that can be weighed directly in air.
    III. It is available in pure form.
    Solution
    $$\begin{array}{l} { H_{ 2 } }{ C_{ 2 } }{ O_{ 4 } }\cdot 2{ H_{ 2 } }O\left( s \right) \to oxadic\, acid\, dihydrate\,  \\ Since,\, it\, is\, very\, stable\, and\, also\, available\, in\, pressure \\ from\, in\, the\, laboratory\, i.e.\, it's\, always\, used\, as\, primary\, s\tan  dard\, in\, the\, lab. \\ Hence,\, the\, option\, C\, is\, the\, correct\, answer. \end{array}$$
  • Question 4
    1 / -0
    The oxidation number of sulphur in $$H_2S_2O_8$$ is:
    Solution
    $$H-O-\overset{\overset{\displaystyle O}{\displaystyle ||}}{\underset{\underset{\displaystyle O}{\displaystyle ||}}{\displaystyle S}}-O-O-\overset{\overset{\displaystyle O}{\displaystyle ||}}{\underset{\underset{\displaystyle O}{\displaystyle ||}}{\displaystyle S}}-O-H$$

    $$\because$$ $$2\ O$$-atoms are in peroxide linkage
    $$\therefore$$ Their oxidation state$$=-1$$
    and, oxidation state of remaining $$6\ O$$-atoms $$=-2$$
    Oxidation state of $$H-$$ atoms $$=+1$$

    Let oxidation state of $$S$$ atom $$=x$$
    $$S_2$$    $$H_2$$     $$O_6$$       $$O_2$$

    $$\therefore 2x+2(+1)+6(-2)+2(-1)=0$$

    $$2x+2-12-2=0$$

    $$\therefore x=+6$$.
  • Question 5
    1 / -0
    Oxidation state of phosphorus in cyclotrimetaphosphoric acid is:
    Solution

    Formula of Trimetaphosphoric acid $$(HPO_3)_3$$
    Oxidation state of $$P$$ is:             (Refer to Image)
    $$3(+1+x+3(-2))=0$$
    $$\Rightarrow x-6+1=0$$
    $$\Rightarrow x= +5$$
    $$+5$$ is the oxidation state of phosphorus in Trimetaphosphoric acid.

  • Question 6
    1 / -0
    A compound of Xe and F is found to have $$53.5\%$$ Xe. What is the oxidation number of Xe in this compound?
    Solution

    Hint: The total number of electrons that an atom acquires or loses in order to form a chemical connection with another atom is known as the oxidation number.

    Explanation:

    Let's say the compound's total weight is $$100\ grams$$.

    As a result, $$53,5\ grams$$ of $$Xe$$ and $$46.7\ grams$$ of $$F$$ are present.

    $$\therefore$$ The number of moles of $$Xe$$ $$=\frac{53.5}{133}=0.4$$ 

    $$\therefore$$ The number of moles of $$F$$ $$=\frac{46.7}{19}=2.45$$.

    Achieving a simple whole-number ratio by dividing both by $$0.4$$.

    Moles of $$Xe$$ $$=\frac{0.4}{0.4}=1$$

    Moles of $$F$$ $$=\frac{2.45}{0.4}=6$$

    As a result, the formula is$$Xe{{F}_{6}}$$.

    $$\therefore$$ $$Xe$$ has an oxidation state of $$+6$$, as $$F$$ has an oxidation state of $$-1$$.

    Final answer:

    The correct answer is option $$(D).$$

  • Question 7
    1 / -0
    The value of n in the molecular formula $$Be_nAl_2Si_6O_{18}$$ is:
  • Question 8
    1 / -0
    Of the following reactions, only one is a redox reaction. Identify this reaction.
    Solution
    Redox reaction means oxidation and reduction reaction must occur simultaneously.

    $$Cu_2S+2FeO\longrightarrow 2Cu+2Fe+SO_2$$

  • Question 9
    1 / -0
    When $$6 \times 10^{22}$$ electrons are used in the electrolysis of a metalic salt, 1.9 gm of the metal is deposited at the cathode The atomic weight of that metal Is 57. So oxidation state of the metal in the salt is:
    Solution
    mol. of $${ e }^{ - }=\dfrac { 6\times { 10 }^{ 22 } }{ 6\times { 10 }^{ 23 } } =0.1$$ mol
    moles of metal $$=\dfrac { 1.9 }{ 57 } =0.033$$ mol
    $${ m }^{ n+ }+n{ e }^{ - }\longrightarrow m$$
    $$\therefore$$  if $$0.1$$ of $${ e }^{ - }$$ is passed and $$0.033$$ mol of $$M$$ is deposited.
    charge $$=\dfrac { 0.1 }{ 0.033 } =+3$$
  • Question 10
    1 / -0
    Which of the following is not a redox reaction?
    Solution
    $$CaCO_{3} \rightarrow CaO + CO_{2}$$

    Since the reaction does not involve oxidation and reduction, it is not a redox reaction.
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