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Redox Reactions Test - 40

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Redox Reactions Test - 40
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  • Question 1
    1 / -0
    Oxidation number of P in $$Ba\, (H_2PO_2)_2$$ is:
    Solution
    $$Ba(H_{2}PO_{2})_{2}$$ is 
    $$Ba(H_{2}PO_{2})_{2}\Rightarrow (H_{2}PO_{2})_{2}^{2-}$$
    $$(+1)\times 2+(x)-2\times 2=-1$$
    $$+2+x-4=-1$$
    $$x=-1+4-2$$
    $$\boxed{x=+1}$$
    So oxidation number of $$P=+1$$
  • Question 2
    1 / -0
    What is the oxidation state of $$Th$$ in organometallic compound $$[ThHOR(C_5Me_5)_2]$$?
    Solution
    Given compound $$[ThHOR(C_5Me_5)_2]$$        $$[ROH^+  ; (+1) - (H); (C_5Me_5)-(-1)]$$
    $$x +1 -2 =0$$
    $$\Rightarrow x - 1 =0$$
    $$\Rightarrow x = +1$$
    Hence, oxidation state of $$Th$$ is $$+1$$
  • Question 3
    1 / -0
    Predict the highest and lowest oxidation state of $$(a)\ Ti$$ and $$(b)\ Tl$$ in combined state.
    Solution
    Outer shell configuration of $$Ti$$ is :
    $$[Ar]3d^24s^2$$
    It minimum state it will remove outer electrons 
    and at maximum it will remove both d and 
    b structures.
    For $$Tl : [Xe]4f^{14}5d^{10}6s^26p^1$$
    For minimum states it will remove p electrons 
    and at maximum all 3 bth shall 
    electrons will be removed.
  • Question 4
    1 / -0
    In Redox reaction:
    $$Fe + HNO_{3}\rightarrow Fe(NO_{3})_{2} + NH_{4}NO_{3} + H_{2}O$$ the coefficient of $$HNO_{3}, Fe(NO_{3})_{2}, NH_{4}NO_{3}$$ is:
    Solution
    After balancing the equation, we get
    $$ 4Fe + 10HNO_3 \rightarrow 4Fe(NO_3)_2 + NH_4NO_3 + 3H_2O$$
    Therefore, Ratio of $$HNO_3,\ Fe(NO_3)_2\ and\  NH_4NO_3 $$is :
    10:4:1.
    Hence, Option B is correct.
  • Question 5
    1 / -0
    The oxidation number of iron in potassium ferricyanide $$[K_{3}Fe(CN)_{6}]$$ is :
    Solution
    To calculate: Oxidation state of iron in potassium ferro cyanide. 
    Solution :
    Oxidation state of Potassium , K = +1
    Oxidation state of Cyanide ion =-1
    Let oxidation state of Iron be x
    We know that sum of all the oxidation states in the compound is equal to overall charge of the compound.
    Therefore, (+1)3 +[ x +6(-1)] = 0
    $$\Rightarrow 3+ [ x-6] =0$$
    $$\Rightarrow x= +6-3 =+3$$
    Hence, the correct option is C.
  • Question 6
    1 / -0
    The ratio of number of moles of $$KMnO_4$$ and $$K_2Cr_2O_7$$ required to oxidise $$0.1$$mol $$Sn^{+4}$$ in acidic medium :
    Solution
    $$\overset { +7 }{ KMnO_4 } \quad \underrightarrow { acidic \quad medium }\quad  \overset { +2 }{ Mn^{+2} } $$
    $$\overset { +6 }{ K_2Cr_2O_7 } \quad \underrightarrow { acidic \quad medium }\quad  \overset { +3 }{ Cr^{+3} } $$
    $$\overset { +4 }{Sn^{+4}  } \quad \underrightarrow { reducing \quad agent}\quad  \overset { +2 }{ Sn^{+2} } $$
    Number of equivalents $$= moles \times nf$$
    $$n(Sn^{+4})=0.1$$
    $$nf(Sn^{+4})=2$$
    Equating number of equivalents of $$KMn{O}_{4}$$ and $${Sn^{+4}}$$
    $${ n }_{ 1 }{ nf }_{ 1 }={ n }_{ 2 }{ nf }_{ 2 }$$
    $$0.1\times 2=5n_{ 2 }\\ n_{ 21 }=0.04$$
    Equating number of equivalents $$K_2$$ $$Cr_2$$ $$O_7$$ and $${Sn^{+4}}$$
    $$n_1f_1=n_22f_22$$
    $$0.1 \times2=6n_{22}$$
    $$n_{22} =\cfrac{0.1} {3}$$
    Ratio of moles of $$KMnO_3$$ and $$K_2 Cr_2 O_7=\cfrac{0.04} {0.1}=\cfrac{6} {5}$$
  • Question 7
    1 / -0
    When benzaldehyde is oxidised to give benzoic acid then the oxidation state of carbon of aldehydic group is changed from:
    Solution
    Bonds between same atoms donot affect the oxidation state. Therefore only functional group affects the oxidation state of $$C$$
    In benzaldehyde:
    $$=O$$ has$$-2$$ and $$H$$ has $$+1$$, therefore in $$CHO$$ O.S. of $$C$$ is: $$x-2+1=0$$
    $$C$$ is $$+1$$
    In Benzoic acid $$=O$$ has$$-2$$ and $$OH$$ has $$-1$$, therefore in $$COOH$$ O.S. of $$C$$ in $$CO-OH$$ is: $$x-2-1=0$$
    $$C$$ is $$+3$$
    Thus O.S. of $$C$$ changes from $$+1$$ to $$+3$$. Option B is correct
  • Question 8
    1 / -0
    The reaction which proceeds in the forward direction is:
    Solution
    $$FeCl_3$$ and $$H_2O$$ do not react to give back $$Fe_3O_4$$ and $$HCl$$.
  • Question 9
    1 / -0
    Which of the following elements never show positive oxidation number?
    Solution
    F is electronegative element . Electronegetivity of F is 4. Therefore F never show positive oxidation number.
  • Question 10
    1 / -0
    Choose the redox reaction from the following.
    Solution
    A redox reaction is the one in which oxidation and reduction take place simultaneously. 
    In option A, 
    $$\cfrac { Cu }{ O } +\cfrac { 2{ H }_{ 2 }{ SO }_{ 4 } }{ +6 } \longrightarrow \cfrac { CuS{ O }_{ 4 } }{ +2 } +\cfrac { { SO }_{ 2 } }{ +4 } +2H_{ 2 }O$$
    Oxidation of $$Cu$$ from $$"0"$$ to $$"+2"$$ and reduction of S from $$"+6"$$ to $$"+4"$$ occurs in the same reaction and hence it is a redox reaction. 
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