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Redox Reactions Test - 46

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Redox Reactions Test - 46
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  • Question 1
    1 / -0
    Oxidation number of three elements $$A,\ B$$ and $$C$$ are $$+2, +3$$ and $$-2$$ respectively. What is the formula of the compound formed from these three elements?
    Solution
    Given, $$A \rightarrow +2, B \rightarrow +3$$ & $$C\rightarrow -2$$
    The formula which satisfies total sum of oxidation states of elements is equal to zero is,
    $$AB_2C_4$$ i.e, $$(+2 \times 1)+(+3\times 2)+(-2 \times 4)$$
                        $$=2+6-8$$
                        $$=0$$ .
  • Question 2
    1 / -0
    Calculate the Oxidation number of $$Co$$ in the compound:
    $$\left[ Co{ \left( { C }_{ 2 }{ O }_{ 4 } \right)  }_{ 2 }{ \left( { NH }_{ 3 } \right)  }_{ 2 } \right] $$
    Solution
    The given molecule has a negative charge on it. So, $$[Co(C_2O_4)_2(NH_3)_2]^{-}$$ and let the oxidation munber of Co be x.
    We know, $$C_2O_4^{2-}$$ is the ion and hence,
    $$\implies x+2\times(-2)=-1 \implies x=+3$$
  • Question 3
    1 / -0
    Oxidation number of $$Cr$$ in $$CrO_5$$ is:
    Solution
    $$\displaystyle CrO_5$$ has one $$\displaystyle Cr=O$$ double bond. The oxygen atom of this double bond has oxidation number of $$\displaystyle -2$$. The remaining 4 oxygen atoms are part of peroxide linkages. The oxygen atom of peroxide linkage has oxidation number of $$\displaystyle -1$$. Let, X be the oxidation number of $$\displaystyle Cr$$
    $$\displaystyle X+(-2)+4(-1)=0$$
    $$\displaystyle X-2-4=0$$
    $$\displaystyle X=+6$$
    Hence, the oxidation number of $$\displaystyle Cr=+6$$
    $$\displaystyle $$

  • Question 4
    1 / -0
    The sum of oxidation states of sulphur in $$H_2S_2O_8$$ is?
    Solution
    Structure of $$H_2S_2O_8$$ is:
    $$HO-\overset { \overset { O }{ || }  }{ \underset { \overset { || }{ O }  }{ S }  } -O-O-\overset { \overset { O }{ || }  }{ \underset { \overset { || }{ O }  }{ S }  } -OH$$
    there is one peroxy linkage $$S-O-O-S$$. Hence two of the eight oxygen atoms have -1 oxidation state and rest 6 have -2 oxidation state. Let the total oxidation state of S be x
    then $$2\times 1+ x+6 \times (-2)+2 \times (-1)=0$$
    or $$2+x-12-2=0$$
    $$x=+12$$
    Sum of oxidation state of both S is x i.e. 12 in $$H_2S_2O_8$$.
  • Question 5
    1 / -0
    Among the following, identify the species with an atom in $$+6$$ oxidation state.
    Solution
    The correct answer is $$(D)\;CrO_2Cl_2$$
    $$Cr+2(O)+2(Cl)=0$$
    $$Cr+2(-2)+2(1)=0$$
    $$Cr=+6$$ 
  • Question 6
    1 / -0
    Oxygen exhibit $$-1$$ oxidation state in:
    Solution
    $${ O }^{ -1 }$$ exist where there is peroxide linkage. Hence $${ H }_{ 2 }O_{ 2 }$$(Hydrogen peroxide).
    $$H-O-O-H$$
  • Question 7
    1 / -0
    In the case of $$CH_3COOH$$, the oxidation number of carbon of the carboxylic group is:
    Solution
    Acetic acid is represented as $$\displaystyle CH_3-\underset {\underset {\displaystyle O}{||}}{C}-OH$$. For the purpose of oxidation number calculation, the oxidation number of C atom of methyl group is considered 0, the oxidation number of oxygen atom of $$\displaystyle C=O$$ double bond is considered $$\displaystyle -2$$. The oxidation number of oxygen atom of hydroxyl group is considered $$\displaystyle -1$$.
    Let $$\displaystyle x$$ be the oxidation number of C atom of carboxylic group.
    $$\displaystyle x+0+(-2)+(-1)=0$$
    $$\displaystyle x-3=0$$
    $$\displaystyle x=+3$$
    Hence, in the case of $$CH_3COOH$$, the oxidation number of carbon of the carboxylic group is $$+3$$.
  • Question 8
    1 / -0
    Which one of the following statements is not correct?
    Solution
    In $$(NH_4)_2S_2O_8$$
    Oxidation state of $$S$$    $$+1(2)+x(2)+(-2\times 8)=0$$
                                            $$2x=14 \Rightarrow x=+7$$

    In $$OsO_4$$
    Oxidation state of $$Os$$   $$x+(-2 \times 4)=0$$
                                           $$x=+8$$

    In $$H_2SO_5$$
    Oxidation state of $$S$$    $$+1(2)+x+(-2)5=0$$
                                            $$x=+8$$
    In $$KO_2$$
    Oxidation state of $$O$$    $$1+(x)2=0$$
                                          $$x=-1/2$$
  • Question 9
    1 / -0
    The oxidation states of Cr in $$\left[ Cr\left( { H }_{ 2 }O \right)  \right] { Cl }_{ 3 },\left[ { Cr\left( { C }_{ 6 }{ H }_{ 6 } \right)  }_{ 2 } \right] ,$$ and $${ K }_{ 2 }\left[ Cr{ \left( CN \right)  }_{ 2 }{ \left( O \right)  }_{ 2 }{ \left( O \right)  }_{ 2 }\left( { NH }_{ 3 } \right)  \right] $$ respectively are :
    Solution
    In the given molecules,
    1. In $$[Cr(H_2O)]Cl_3$$, let oxidation number of Cr be x, Here the molecule separates as its ions as, $$[Cr(H_2O)]^{3+}$$ and  $$3Cl^{-}$$. As $$H_2O$$ is a neutral molecule its oxidation number is zero. Hence, $$x=+3$$
    2. In $$[Cr(C_6H_6)_2]$$ let oxidation number of Cr be y, Benzene is a neutral molecule and hence on observing the cross multiplied factor we get the oxidation number of Cr as 0. Hence,$$y=0$$.
    3. In $$K_2[Cr(CN)_2(O)_2(NH_3)]$$,let oxidation number of Cr be z, Here the ions are- $$2K^{+}$$ and $$[Cr(CN)_2(O)_2(NH_3)]^{2-}$$. As  $$NH_3$$ is neutral molecule and $$O^{-}$$and  $$CN^{-}$$ is $$2 \times (-1)+4 \times (-1)=-6$$ and hence oxidation number of Cr is, z-6=-0$$\implies z=+6$$
    Hence,option C is correct answer.

  • Question 10
    1 / -0
    Calculate the Oxidation number of $$Fe$$ in the compound.
    $$\left[ Fe\left( { No } \right) { ({ H }_{ 2 }O )}_{ 5 } \right] { SO }_{ 4 }$$
    Solution
    Let the oxidation number of Fe in the given compound $$[Fe(No)(H_2O)_5]SO_4$$ be x
    As it dissociated into ions then we get, $$[Fe(No)(H_2O)_5]^{2+}$$ and $$SO_4^{2-}$$
    We know No exists as $$No^{-}$$ and hence oxidation state of Fe is,
    $$x-1=+2 \implies x=+3$$
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