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Redox Reactions Test - 9

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Redox Reactions Test - 9
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  • Question 1
    1 / -0

    Which of the following is not an example of redox reaction?

    Solution

    Oxidation no. of all the elements remains unchanged.

  • Question 2
    1 / -0

    The more positive the value of \(E^{\ominus}\), the greater is the tendency of the species to get reduced. Using the standard electrode potential of redox couples given below find out which of the following is the strongest oxidising agent.

    \(E^{\ominus}\) values: \(Fe^{3+}\)/\(Fe^{2+}\) = +0.77; \(I_2\)(s)/\(I^-\) = +0.54;

    \(Cu^{2+}\)/Cu = +0.34; \(Ag^+\)/Ag = +0.80V

    Solution

    \(Ag^+\)/Ag has highest value of reduction potential.

  • Question 3
    1 / -0

    \(E^{\ominus}\) values of some redox couples are given below. On the basis of these values choose the correct option.

    \(E^{\ominus}\) values: \(Br_2\)/\(Br^-\) = +1.90; \(Ag^+\)/Ag(s) = +0.80

    \(Cu^{2+}\)/Cu(s) = +0.34; \(I_2(s)\)/\(I^-\) = +0.54

    Solution

    \(Br_2\) is better oxidizing agent than \(Cu^{2+}\).

  • Question 4
    1 / -0

    Using the standard electrode potential, find out the pair between which redox reaction is not feasible.

    \(E^{\ominus}\) values: \(Fe^{3+}\)/\(Fe^{2+}\) = +0.77; \(I_2\)/\(I^-\) = +0.54;

    \(Cu^{2+}\)/Cu = +.034; \(Ag^+\)/Ag = +0.80 V

    Solution

    \(E^0_{cell}\) will be negative for the pair Ag and \(Fe^{3+}\). Hence the reaction is not feasible.

  • Question 5
    1 / -0

    Thiosulphate reacts differently with iodine and bromine in the reactions given below:

    \(2S_2O^{2-}_3+I_2\) → \(S_4O^{2-}_6+2I^-\)

    \(S_2O^{2-}_3+2Br_2+5H_2O\) → \(2SO^{2-}_4+2Br^-+10H^+\)

    Which of the following statements justifies the above dual behaviour of thiosulphate?

    Solution

    Standard reduction potential of bromine is higher than Iodine.

  • Question 6
    1 / -0

    Which of the following statement(s) is/are not true about the following decomposition reaction.

    \(2KClO_3\) → 2KCl + 3\(O_2\)

    (i) Potassium is undergoing oxidation

    (ii) Chlorine is undergoing oxidation

    (iii) Oxygen is reduced

    (iv) None of the species are undergoing oxidation or reduction

    Solution

    Potassium remains in same oxidation state and oxygen is being oxidized.

  • Question 7
    1 / -0

    In the following questions a statement of Assertion (A) followed by a statement of Reason (R) is given. Choose the correct option out of the choices given below each question.

    Assertion (A): Among halogens fluorine is the best oxidant.

    Reason (R): Fluorine is the most electronegative atom.

    Solution

    Fluorine is most electronegative element that is why it is best oxidant among halogens.

  • Question 8
    1 / -0

    Match Column I with Column II for the oxidation states of the central atoms.

    Column I Column II
    (i) \(Cr_2O^{2-}_7\) (a) +3
    (ii) \(MnO^-_4\) (b) +4
    (iii)\(VO^-_3\) (c) +5
    (iv) \(FeF^{3-}_6\) (d) +6
      (e) +7
  • Question 9
    1 / -0

    Identify the correct statement (s) in relation to the following reaction:

    Zn + 2HCl → Zn\(Cl_2\) + \(H_2\)

    (i) Zinc is acting as an oxidant

    (ii) Chlorine is acting as a reductant

    (iii) Hydrogen ion is acting as an oxidant

    (iv) Zinc is acting as a reductant

    Solution

    Zinc is oxidized in the reaction and hydrogen is reduced.

  • Question 10
    1 / -0

    The oxidation number of an element in a compound is evaluated on the basis of certain rules. Which of the following rules is not correct in this respect?

    Solution

    In ionic hydrides hydrogen exist in -1 oxidation state because the hydrogen acquires negative charge in the presence of its companion.

  • Question 11
    1 / -0

    In which of the following compounds, an element exhibits two different oxidation states.

    Solution

    Nitrogen exists in two different oxidation states i.e., +5 and -3.

  • Question 12
    1 / -0

    The exhibition of various oxidation states by an element is also related to the outer orbital electronic configuration of its atom. Atom(s) having which of the following outermost electronic configurations will exhibit more than one oxidation state in its compounds?

    (i) 3\(s ^1\)

    (ii) 3\(d ^1\)4\(s ^2\)

    (iii) 3\(d ^2\)4\(s ^2\)

    (iv) 3\(s ^2\)3\(p ^3\)

    Solution

    In option (iii) electron can be removed from 4s as well as 3d. Similarly, in option (iv) electron can be removed from 3p and 3s both.

  • Question 13
    1 / -0

    Which of the following arrangements represent increasing oxidation number of the central atom?

    Solution

    Oxidation no. of central element increases as +3, +5, +6, +7.

  • Question 14
    1 / -0

    The largest oxidation number exhibited by an element depends on its outer electronic configuration. With which of the following outer electronic configurations the element will exhibit largest oxidation number?

    Solution

    Total no. of electrons present in d and s subshell = 7

  • Question 15
    1 / -0

    Identify the correct statements with reference to the given reaction:

    \(P_4\) + \(3OH^-\) + \(3H_2O\) → \(PH_3\) + \(3H_2\)\(PO^-_2\)

    (i) Phosphorus is undergoing reduction only 

    (ii) Phosphorus is undergoing oxidation only 

    (iii) Phosphorus is undergoing oxidation as well as reduction

    (iv) Hydrogen is undergoing neither oxidation nor reduction

    Solution

    This is a kind of disproportionation reaction in which phosphorous is being reduced as well as oxidized whereas hydrogen remains same in +1 oxidation state.

  • Question 16
    1 / -0

    In the following questions a statement of Assertion (A) followed by a statement of Reason (R) is given. Choose the correct option out of the choices given below each question.

    Assertion (A): In the reaction between potassium permanganate and potassium iodide, permanganate ions act as oxidising agent.

    Reason (R): Oxidation state of manganese changes from +2 to +7 during the reaction

    Solution

    As permanganate ion changes to \(MnO_2\).

  • Question 17
    1 / -0

    Which of the following electrodes will act as anodes, when connected to Standard Hydrogen Electrode?

    (i) Al/\(Al^{3+}\)      \(E^{\ominus}\) = -1.66

    (ii)  Fe/\(Fe^{2+}\)  \(E^{\ominus}\) = -0.44

    (iii) Cu/\(Cu^{2+}\)  \(E^{\ominus}\) = +0.34

    (iv) \(F_2\)(g)/2\(F^-\)(aq)   \(E^{\ominus}\) = +2.87

    Solution

    Both has negative value of standard reduction potential.

  • Question 18
    1 / -0

    Identify disproportionation reaction

    Solution

    Oxidation no. of nitrogen decrease by 1 from \(NO_2\) to \(NO_2^-\) and increase by +1 from \(NO_2\) to \(NO_3^-\).

  • Question 19
    1 / -0

    Which of the following elements does not show disproportionation tendency?

    Solution

    Fluorine is the most electronegative element.

  • Question 20
    1 / -0

    Match the items in Column I with relevant items in Column II.

    Column I Column II
    (i) Ions having positive charge (i) +7
    (ii)The sum of oxidation number of all atoms in a neutral molecule (ii) -1
    (iii)Oxidation number of hydrogen ion (\(H ^+ \)) (iii) +1
    (iv)Oxidation number of fluorine in NaF (d) 0
    (v) Ions having negative charge (e) Cation
      (f) Anion
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