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Aldehydes Ketones and Carboxylic Acids Test - 30

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Aldehydes Ketones and Carboxylic Acids Test - 30
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Weekly Quiz Competition
  • Question 1
    1 / -0
    Which of the following chemical is used in making metal polishes:
    Solution
    Uses of oxalic acid are: 
    Bleaching agent in textile activities, 
    Marble polishing 
    Purifying agent in pharmaceutical industries
  • Question 2
    1 / -0
    Which acid is used as table vinegar?
    Solution
    Acetic acid is also called as vinegar.
  • Question 3
    1 / -0
    Which of the following is not a use of benzoic acid?
    Solution
    Benzoic acid is used as food preservatives, antiseptic and for dyes. But not for metal polish.
    Oxalic acid is used in making metal polish.
  • Question 4
    1 / -0
    Acid present in honey bee sting is:
    Solution
    Formic acid is present in honey bee sting which is used for Chemo communication.
  • Question 5
    1 / -0
    The general formula $${ C }_{ n }{ H }_{ 2n }{ O }_{ 2 }$$ could be for open chain
    Solution
    $${ C }_{ n }{ H }_{ 2n }{ O }_{ 2 }$$ is the general formula for open chain carboxylic acid and ester e.g if $$n=3\Rightarrow { C }_{ 3 }{ H }_{ 6 }{ O }_{ 2 }$$
    Ester-$${ CH }_{ 3 }COO{ CH }_{ 3 }$$
    Acid-$${ CH }_{ 3 }{ CH }_{ 2 }COOH$$
  • Question 6
    1 / -0
    Which of the following statements is incorrect regarding the reaction?

    $$CH_3CHO+[Ag(NH_3)_2]^{\oplus} + \bar{OH} \rightarrow CH+3COO^-+Ag$$
    Solution
    Oxidation:

    $$CH_3CHO+3\bar{OH} \rightarrow CH_3COO^-+2e+2H_2O$$     ...(i)

    Reduction :

    $$\{Ag(NH_3)_2]^++e^{\oplus}\rightarrow Ag+2NH_3\}\times 2$$     ...(ii)

    $$\therefore CH_3CHO+[Ag(NH_3)_2]^{\oplus}+3\bar{OH}\rightarrow CH_3COO^-+2H_2O+2Ag+4NH_3$$

    Molecular mass of $$CH_3CHO=44$$

    Equivalent weight $$=\dfrac{MW}{n-factor}=\dfrac{44}{2}=22$$

    Therefore, acetaldehyde reducing agent

    Hence, the correct option is $$\text{C}$$
  • Question 7
    1 / -0
    $$C_nH_{2n-1}COOH$$ is the general formula for:
    Solution
    $$C_nH_{2n-1}COOH$$ is a general formula for unsaturated fatty acids.
    For example: $$CH_2=CH-COOH$$
    Propenoic acid $$C_2H_3COOH$$
    $$C_nH_{2n+1}COOH$$ is general formula for saturated fatty acids.
    For example: $$CH_3COOH$$ is Ethanoic acid.
  • Question 8
    1 / -0
    Reduction of ketones cannot be carried out with which of the following reagents?
    Solution
    Reduction of ketones cannot be carried out with hydrogen in presence of palladium in Barrium sulphate and quinoline. This reagent is Lindlar's catalyst and is used for selective reduction of alkyne to trans alkene.

    In Clemmensen's reduction, zinc amalgam and concentrated HCl converts carbonyl group to methylene group.

    in Wolf Kishner's reduction, Hydrazine and KOH in ethylene glycol converts carbonyl group to methylene group.

    Sodium borohydride or Lithium Aluminium hydride reduces keto groups to alcohols.
  • Question 9
    1 / -0
    One girl student uses the liquid compound to remove nail paint from her nail. The liquid compound removes the nail paint from her nail. Give the name of this compound.
    Solution
    Propanone also called acetone is used to remove nail paint from the nail.

    Acetone is a volatile, flammable and colorless liquid that is miscible with water. On the other hand, nail polish remover is an organic solvent that may include coloring, scents, oils, and solvents.

    Option D is correct.
  • Question 10
    1 / -0
    Which of the following is crossed aldol product in the reaction?
    $$CH_3CHO+CH_3CH_2CHO\xrightarrow[25^oC]{OH^-}$$ $$'P'$$
    Solution

    Ethanal is more electrophilic than propanal. So, enolate of propanal will attack as nucleophile on ethanal.

    The product formed is $$\beta- hydroxy\ aldehyde$$ , given in option C. 

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