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Electrochemistry Test - 25

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Electrochemistry Test - 25
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  • Question 1
    1 / -0
    Which of the following is true for electrolytic refining?
    Solution
    Impure metal will release electron hence form anode electrode and pure metal will absorb electron hence it will be posses as cathode electrode.

    Pure metal is used as the cathode and impure metal as anode.
  • Question 2
    1 / -0
    The electric current in a chemical cell is due to movement of :
    Solution
    An electrolyte solution is formed by mixing an electrolyte in a solvent. The electrolyte on dissolution furnishes ions. The preferred movement of ions under the influence of the electric field is responsible for electric current. Hence, the electric current in a chemical cell is due to the movement of positive and negative ions.

    Therefore option D is correct.
  • Question 3
    1 / -0
    The internal resistance of a dry cell is of the order of:
    Solution
    In dry-cell battery, the electrolyte is in the form of a paste. And there is no presence of nickel and iron material. Due to that, the internal resistance of the dry is very less. The value is approximately in between 0.2 to 0.4 $$\Omega.$$
  • Question 4
    1 / -0
    An example of secondary battery cell is:
    Solution
    Voltiac cell, daniel cell, Lachanche cell, Bunsen cell, fuel are some well known example of primary battery cells. Whereas, lead acid cell and edison alkaline cell are two well known example of secondary cells.
  • Question 5
    1 / -0
    Molten $$AlCl_3$$ is electrolysed with the current of $$0.5 $$ empere to produced 27 g $$Al$$. Number of Farady used are :
    Solution
    $$Al^{3+} + 3e^- \rightarrow Al $$
    From Faraday's laws of electrolysis, we know that
    $$W= \frac{EQ}{96500} $$.
    $$ \frac{Q}{96500} =\dfrac {W}{E}$$.
    $$E = 27/3 = 9 $$.
    $$\frac {Q}{96500} = 27/9 = 3F $$.
    Hence option A is the right answer.
  • Question 6
    1 / -0
    In electrolysis experiment, after some times, the battery connection is reversed. Then 
    Solution
    Due to the reverse connection of the battery, only the polarities of the electrode change but the electrolysis process continues to take place and the rate of liberation of materials at the electrode will not change.
  • Question 7
    1 / -0
    Internal resistance of a battery cell increases with :
    Solution
    Internal resistance of a battery cell:
    1) i
    ncreases with increase in distance between two electrodes.
    2) decreases with increase in concentration of electrolyte.
    3) decreases with increase in area of the plate inside the electrolyte.
    4) decreases with increase in size of the electrodes.
  • Question 8
    1 / -0
    The electric charge for electrode deposition of 1 g equivalent of a substance is:
    Solution
    Charge on one mole of electrons is equal to one Faraday, so one gram equivalent of a substance will be deposited by one mole of electrons.

    g equivalent of a substance means one equivalent of substance which have total charge of one mole of electron.
  • Question 9
    1 / -0
    The half cell involving the reaction $$Cr_2O_7^{2-} (aq) + 14 H^+ (aq) + 6e   \rightarrow 2Cr^{3+} (aq) + 7H_2O$$ can be represented as :
    Solution
    It is reduction half cell of $$Cr_2O_7^{-2}$$ and is represented as: 
    $$(Pt), H^+, Cr_2O_7^{2-} (aq), Cr^{3+} (aq)$$
  • Question 10
    1 / -0
    In the atmosphere of industrial smog, copper corrodes to form:
    Solution
    Architectural structures built with copper corrode to give green verdigris (copper carbonate). It can be a mixture of carbonate and sulfate compounds in various amounts, depending upon environmental conditions such as sulfur-containing acid rain.
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