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Electrochemistry Test - 31

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Electrochemistry Test - 31
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  • Question 1
    1 / -0
    If $$m$$ is the mass of silver deposited at the cathode by $$2 A$$ current flowing for $$25 min$$ through a silver voltameter, then the mass deposited by $$1.5 A$$ current flowing for $$600 s$$ is _________.
    Solution
    $$\displaystyle \frac {{m}'}{m} = \frac {{I}'{t}'}{It} = \frac {1.5 \times 600}{2 \times 25 \times 60} = \frac {900}{3000} = \frac {3}{10} = 0.3$$

    $$\Rightarrow {m}'=0.3m$$
  • Question 2
    1 / -0
    The liberation of $$1$$ mole of chlorine requires how many Faradays of electricity?
    Solution
    $$2Cl^- \rightarrow Cl_2 + 2e^-$$
    $$Q={n(e^-)}\times {F}$$ 
    2mol electrons are liberated in production of 1mol of chlorine.
    therefore electricity required for the process 
    $$\Rightarrow$$ $$= {2}\times {F}$$ = $$2$$ Faradays
  • Question 3
    1 / -0
    A voltaic cell is represented as $${A}_{(s)}\left| { { A }^{ +2 } }_{ (aq) } \right| \left| { { B }^{ +2 } }_{ (aq) } \right| {B}_{(s)}$$. Which of the following statements of false regarding the above cell?
    Solution
    Cell diagram is represented as
    $$\underset{Anode} {A_{(s)}}\left| \underset {Oxidation}{{ A }^{ +2 }}_{ (aq) } \right| \left| \underset{Cathode} {{ B }^{ +2 }_{ (aq)}}  \right| \underset {Reduction}{B}_{(s)}$$.
    The cell reactions are represented as $${A}\rightarrow {A}^{+2} + 2e^-$$ and $$B^{+2} + 2e^-\rightarrow {B}$$
  • Question 4
    1 / -0
    In an electrolyte, $$3.2 \times 10^{18}$$ bivalent positive ions drift to the right per second while $$3.6 \times 10^{18}$$ monovalent negative ions drift to the left per second. The current through the electrolyte is _______.
    Solution
    Current $$I =$$ net charge transported/second
    $$= 3.2 \times 10^{18} \times 2e + 3.6 \times 10^{18} \times e$$
    $$= (6.u + 3.6) \times 10^{18} \times 1.6 \times 10^{-19}$$
    $$= 10 \times 1.6 \times 10^{-1}$$
    $$= 1.6 A$$ to the right.
  • Question 5
    1 / -0
    Lead pipes are readily corroded by:
    Solution
    Corrosion of lead is strongly accelerated by traces of acetic acid. Acetic acid in the presence of oxygen rapidly attacks lead and produces very soluble lead(II) acetate which precludes the use of lead to process or store wine or fruit juice.
  • Question 6
    1 / -0
    If copper is kept open in air, it slowly loses its shining brown surface and gains a green coating. It is due to the formation of:
    Solution
    Copper reacts with $$CO_2$$ present in the air and forms a green coating on its surface due to the formation of basic copper carbonate.

    $$2Cu+O_2+CO_2+H_2O\rightarrow CuCO_3.Cu(OH)_2$$

    So, the correct option is $$C$$
  • Question 7
    1 / -0
    According to the electrochemical concept, corrosion occurs at :
    Solution
    Corrosion can be defined as the deterioration of materials by chemical processes. 
    Of these, the most important by far is electrochemical corrosion of metals in which the oxidation process $$M \rightarrow M^+ + e^-$$ is facilitated by the presence of a suitable electron acceptor. This is possible because metals are conductive and so, the electrons can flow through the metal from the anodic to the cathodic regions. 
    Metallic corrosion occurs when metal atoms are oxidized and subsequently leave the metal lattice as ions. The oxidation reaction of the metal is referred to as the anodic half-reaction. The areas on a metal surface where oxidation occurs are referred to as anodes.

    Option A is correct.
  • Question 8
    1 / -0
    As dilution of the solution increases then the conductivity of solution ___________.
    Solution
    The conductivity of a weak electrolyte increases with an increase dilution. As the dilution increases the number of ion increases and they get free from their co-ions and can move independently from each other. So by increasing dilution the rate of conductivity increases as more ions are available for conductance 
  • Question 9
    1 / -0
    The hydrogen formed by the action of zinc on sulphuric acid forms a layer of gas on the surface of copper plate in a simple voltaic cell, because of which
    Solution
    The hydrogen formed by the action of zinc on sulphuric acid forms a layer of gas on the surface of a copper plate in a simple voltaic cell, because of which:-
    $$\rightarrow$$ Internal resistance of cell increases
    $$\rightarrow$$ Hydrogen ions are unable to reach the anode
    $$\rightarrow$$ polarisation takes place at an anode.
  • Question 10
    1 / -0
    When a corroded metal object is rubbed by a sand paper then:
    Solution
    The metals lose their shine and become dull when exposed to air for a long time. Due to the formation of oxides, when the surface is rubbed by a sand paper, then the outer corroded layer is removed.
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