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Electrochemistr...

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  • Question 1
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    An electrochemical cell can behave like an electrolytic cell when:

  • Question 2
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    In the electrolysis of aqueous sodium chloride solution which of the half-cell reaction will occur at the anode?

  • Question 3
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    The reaction, $$2B{r^ - }\left( {aq} \right) + S{n^{2 + }}\left( {aq} \right) \to B{r_2}\left( 1 \right) + Sn\left( s \right)$$ with the standard potentials,$$E{^\circ _{Sn}} =  - 0.114V,\,E{^\circ _{B{r_2}}} =  + 1.09V$$, is:

  • Question 4
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    Half cell reactions for some electrodes are given below:
    I. $$A+{ e }^{ - }\longrightarrow { A }^{ - }\  ;\quad \quad \  { E }^{ 0 }=0.96V$$
    II. $${ B }^{ - }+{ e }^{ - }\longrightarrow { B }^{ 2- }\  ;\quad { E }^{ o }=-0.12V$$
    III. $${ C }^{ + }+{ e }^{ - }\longrightarrow C\  ;\quad \  { E }^{ o }=+0.18V$$
    IV. $${ D }^{ 2+ }+{ 2e }^{ - }\longrightarrow D\  ;\quad  { E }^{ o }=-1.12V$$

    The largest potential will be generated in which cell?

  • Question 5
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    Which of the following relation is not correct?

  • Question 6
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    Chromium metal can be plated out from an acidic solution containing $$CrO_3$$ according to the following equation $$CrO_3(aq)+6H^+(aq)+6e^-\rightarrow Cr(s)+3H_2O$$
    Calculate how many grams of chromium will be placed out by $$24000$$ coulombs (Atomic Weight of Cr$$=52$$).

  • Question 7
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    What would you observe if you set up the following electrochemical cell
    $${\text{Ag|Agn}}{{\text{o}}_3}\left( {0.001M} \right)||AgN{O_3}(1M)|Ag$$

  • Question 8
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    A constant electric current flows for 4 hours through two electrolytic cells connected in series. One contains $$AgNO_3$$ solution and second contains $$CuCl_2$$ solution. During this time, 4 grams of $$Ag$$ is deposited in the first cell. How many grams of Cu is deposited in the second cell?

  • Question 9
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    $$Cd$$ amalgam is prepared by electrolysis of a solution of $$CdCl_2$$ using a mercury cathode. Current of how much ampere must be passed for $$100$$ seconds in order to prepare $$20\%$$ $$Cd-Hg$$ amalgam on a cathode of $$2$$ g mercury? (At. wt. of Cd$$=112.40$$)

  • Question 10
    1 / -0

    Given below are the half-cell reactions:
    $$Mn^{2+} + 2e^- \to Mn; E^o = -1.18V$$
    $$2(Mn^{3+} + e^- \to Mn^{2+}); E^o = +1.51V$$
    The $$E^o$$ for $$3Mn^{2+} \to Mn +2Mn^{3+}$$ will be:

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