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Electrochemistr...

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  • Question 1
    1 / -0

    In electrolysis of NaCl when Pt electrode is taken then $${ H }_{ 2 }$$ is liberated at the cathode while with Hg cathode it forms sodium amalgam, because:

  • Question 2
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    How long (approximate) should water be electrolysed by passing through $$100$$ amperes current so that the oxygen released can completely burn $$27.66\ g$$ of diborane?
    [Atomic weight of $$B=10.8\ u$$]

  • Question 3
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    In the electrolysis of $$AgNO_3$$ solution 0.7 g of Ag is deposited after a certain period of time. Calculate the quantity of electricity required in coulomb. Molar mass of Ag is $$107.9 g mol^{-1}$$.

  • Question 4
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    Based on the cell notation for spontaneous reaction, at the anode:
    $$Ag(s)|AgCl(s)|{ Cl }^{ - }(aq)\parallel { Br }^{ - }(aq)|{ Br }_{ 2 }(I)|C(s)$$

  • Question 5
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    $$10800\ C$$ of electricity through the electrolyte deposited $$2.977\ g$$ of metal with atmic mass $$106.4\ g\ mol^{-1}$$. The charge on the metal cation is:

  • Question 6
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    $$Al_2O_3$$ is reduced by electrolysis at low potentials and high currents. If $$4.0\times 10^4$$ amperes of current is passed through molten $$Al_2O_3$$ for $$6$$ hours, what mass of aluminium is produced? 

    (Assume $$100\%$$ current efficiency and atomic mass of $$Al$$ $$=27$$ g $$mol^{-1}$$)

  • Question 7
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    If a $$100 \; mL$$ solution of $$0.1M$$. $$HBr$$ is titrated using a very concentrated solution of $$NaOH$$, then the conductivity (specific conductance) of this solution at the equivalence point will be:

    (assume volume change is negligible due to the addition of $$(NaOH)$$. Report your answer after multiplying it with 10 in $$Sm^{-1}$$.
    [Given: $$\lambda^{\circ}_{(Na^+)}  = 8 \times 10^{-3}  Sm^2  mol^{-1}, 
    \lambda^{\circ}_{(Br^-)}  = 4 \times 10^{-3}  Sm^2  mol^{-1}$$]

  • Question 8
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    The number of coulombs necessary to deposit 1 g of potassium metal (molar mass $$39 g mol^{-1}$$) from $$K^+ ions$$ is:

  • Question 9
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    When $$9.65$$ ampere current was passed for $$1.0$$ hour into nitrobenzene in acidic medium, the amount of p-aminophenol produced is:

  • Question 10
    1 / -0

    The charge required to deposit $$40.5 \,g$$ of $$Al$$ (atomic mass $$= 27.0 \,g$$) from the fused $$Al_2(SO_4)_3$$ is:

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