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Chemical Kineti...

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  • Question 1
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    First order reaction completes $$20\%$$ in $$5$$ min. How much time it will take for $$60\%$$ completion?

  • Question 2
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    A first order reaction takes $$40$$ min for $$30$$% decomposition. What will be $$t_{1/2}$$?

  • Question 3
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    Cyclopropane rearranges to form propene:

    $$\triangle \rightarrow CH_{2} - CH = CH_{2}$$

    This follows first-order kinetics. The rate constant is $$2.714\times 10^{-3} sec^{-1}$$. The initial concentration of cyclopropane is $$0.29\ M$$. What will be the concentration of cyclopropane after $$100\ sec$$?

  • Question 4
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    The reaction $$2X \rightarrow Y + Z$$ would be zero order reaction when:

  • Question 5
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    The decomposition of a substance follows first order kinetics. If its concentration is reduced to $$1/8$$ of its initial value in $$12$$ minutes, the rate constant of the decomposition system is ?

  • Question 6
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    For the first order reaction,
    $$2H_2O_2\rightarrow 2H_2\,+\,O_2 \,\log k\,=\,14.34\,-\,1.25\,\times\,10^4\,K/T$$. The energy of activation for the above reaction if its half life period is 256 min.

  • Question 7
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    At low pressure, the fraction of the surface covered follows:

  • Question 8
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    The following data were obtained during the first order thermal decomposition of $$SO_2Cl_2$$ at constant volume
    $$SO_2Cl_{2(g)} \rightarrow SO_{2(g)}\,+\,Cl_{2(g)}$$

    ExptTime / $$S^{-1}$$Total pressure/ atm
    100.5
    21000.6
    when the total pressure is 0.65 atm then the rate constant of reaction is ..............
     if a = pi, and a - x = 2pi - Pt

  • Question 9
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    The rate constant of a first order reaction is $$15\times 10^{-3} s^{-1}$$. How long will $$5.0\ g$$ of this reactant take to reduce to $$3.0\ g$$?

  • Question 10
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    The half-life of the reaction $$X\rightarrow Y$$, following first-order kinetics, when the initial concentration of $$X$$ is $$0.01$$ mol L$$^{-1}$$ and the initial rate is $$0.00352$$ mol L$$^{-1}$$ min$$^{-1}$$ will be :

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