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Chemical Kineti...

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  • Question 1
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    For a first order reaction, the ratio of the time taken for $$7/8^{th}$$ of the reaction to complete to that of half of the reaction to complete is :

  • Question 2
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    A first order reaction is $$50$$% complete in $$30$$ minutes at $$27^{\circ}C$$ and in $$10$$ minutes at $$47^{\circ}C$$. The reaction rate constant at $$27^{\circ}C$$ and the energy of activation of the reaction are respectively.

  • Question 3
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    Threshold energy is equal to:

  • Question 4
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    In the reaction, $$2NO+Cl_2\rightarrow 2NOCl$$, it has been found that doubling the concentration of both the reactants increases the rate by a factor of eight but doubling the chlorine concentration alone only doubles the rate. Which of the following statements is incorrect?

  • Question 5
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    The rate constant is given by the equation $$k = P.Ze^{-E_{a}/RT}$$. Which factor should register $$a$$ decrease for the reaction to proceed more rapidly:

  • Question 6
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    Fill up the following with suitable terms.

    (i) Activation energy $$=$$ Threshold energy $$-$$ _______.

    (ii) Half-life period of zero order reaction $$=$$ ________.

    (iii) Average rate of reaction $$=$$ _______.

    (iv) Instantaneous rate of reaction $$=$$ ______.

  • Question 7
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    The rate of a particular reaction doubles when temperature change from  $${ 27 }^{ 0 }$$C to $${ 37 }^{ 0 }$$C. Calculate the energy of the activation of such reaction.

  • Question 8
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    For an elementary bi-molecular reaction of the type $$A + B \rightarrow C$$ activation energy is equal to 20 Kcal. If specific rate of reaction at 500 K is 4.2 $$\times$$ $$10^{-3}M^{-1}sec^{-1}$$, then identify the incorrect option(s). [Given : ln ($$2.1 \times$$ $$10^{-9}$$) = - 20] 

  • Question 9
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    The activation energy for the forward reaction X Y is $$60$$ KJ $$mol^{-1}$$ and $$\Delta H$$ is $$-20$$ KJ $$mol^{-1}$$. The activation energy for the backward reaction Y X is:

  • Question 10
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    The half-life of a first-order reaction is $$100$$ seconds. What is the time required in seconds for $$90\%$$ completion of the reaction?

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