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Chemical Kineti...

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  • Question 1
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    The rates of most reactions doubled when their temperature is raised from $$298\ K$$ to $$308\ K$$, calculate their activation energy?

  • Question 2
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    A first order reaction goes upto 8% in 10 min. What time will it take to complete 99%

  • Question 3
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     If a reaction follows the Arrhenius equation, the plot $$lnK$$ vs $$ \dfrac{1}{(RT)}$$  gives a straight line with a gradient $$(-y)$$ unit. The energy required to activate the reactant is : 

  • Question 4
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    The catalysts decrease the Ea from $$100 KJmol^-1$$ to $$80 KJmol^-1$$. At what temperature the rate of reaction in the absence of catalyst at 500 K will be equal to the rate of reaction in the presence of a catalyst .

  • Question 5
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    The reaction, $$X \rightarrow Y$$ is an exothermic reaction. Activation energy of the reaction for conversation of $$x$$ into $$Y$$ is $$150kJ mol^{-1}$$. Enthalpy is $$135 kJ mol^{-1}$$. The activation energy for the reverse reaction, $$Y \rightarrow X$$ will be

  • Question 6
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    Consider the following in respect of zero-order reaction
    i. $${ t }_{\frac{1}{2} }$$ is directly proportional to the initial concentration
    ii. Time taken for the completion of the reaction is twice its $${ t }_{ 1/2 }$$
    iii. Concentration of the reactant decreases linearly with time
    Which of the statements given above are correct?

  • Question 7
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    If the values of enthalpies of reactants and products are p and q J/mol respectively. If the activation energy for the backward reaction is r J/mol, then the activation energy for forward reaction will be in (J/mol) (take only magnitudes)

  • Question 8
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    The rate  law of the reaction A + 2B $$\rightarrow $$ product is given by $$\frac{d(product)}{dt} = k[A]^2[B]$$. If $$A$$ is taken in large excess, the order of the reaction will be:

  • Question 9
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    For the decomposition of $${ N }_{ 2 }{ O }_{ 5 }(g)$$ it is given that - $${ 2N }_{ 2 }{ O }_{ 5 }(g)\longrightarrow 4{ NO }_{ 2 }(g)$$ Activation energy = Ea, $${ N }_{ 2 }{ O }_{ 5 }(g)\longrightarrow { 2NO }_{ 2(g) }+\frac { 1 }{ 2 } { O }_{ 2 }(g)$$ activation energy =$${ E }a^{ ' }$$then 

  • Question 10
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    For a first order reaction, the ratio of time for the completion of 99.9% and half of the reaction is

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