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The p-Block Elements Test - 54

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The p-Block Elements Test - 54
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Weekly Quiz Competition
  • Question 1
    1 / -0
    Which of the following elements occur free in nature?
    Solution
    The nitrogen which exists free in nature which is made up of 78% of Earth atmosphere and naturally found in mineral deposits, soil and organic compounds.
  • Question 2
    1 / -0
    Which of the following displaces $$Br_{2}$$ from an aquenous solution containing bromide ions?
    Solution
    chlorine displaces bromine from an aqueous solution containing bromide
    Reactivity of chlorine is more than that of bromine. So chlorine replaces Bromine.
    Hence answer is option B
  • Question 3
    1 / -0
    Which of the following has $$p\pi -d\pi$$ bonding? 
    Solution
    $$p\pi-d\pi$$ bonding includes d-orbitals,if you observe the options only S belongs to $$3^{rd}$$ period and has d-orbitals(though unoccupied in ground state).
    Other options $$C$$ and $$N$$ belongs to $$2^{nd}$$ period while B belongs to $$1^{st}$$ period and doesn't have d-orbitals.
  • Question 4
    1 / -0
    In Haber's process of manufacturing of ammonia:
    $${ N }_{ 2 }\left( g \right) +{ 3H }_{ 2 }\left( g \right) \longrightarrow 2{ NH }_{ 3 }\left( g \right) ;{ H }_{ { 25 }^{ 0 }C }^{ o }=-92.2kJ$$
    Molecule: $${ C }_{ p }{ JK }^{ -1 }{ mol }^{ -1 }$$
    $${ N }_{ 2 }\left( g \right) $$: 29.1
    $${ H }_{ 2 }\left( g \right) $$: 28.8
    $${ NH }_{ 3 }\left( g \right) $$: 35.1 
    If $${ C }_{ p }$$ is independent of temperature, then reaction at $${ 100 }^{ 0 }C$$ as compared to that of $$25^{ 0 }C$$ will be:
    Solution

  • Question 5
    1 / -0
    $$p\pi -d\pi \quad$$ bonding is present in:
    Solution
    So, $$1p\pi - d\pi$$ bonding is present is it.
    The structure of $$SO_3^2-$$ is

  • Question 6
    1 / -0
    $$NH_3$$ is formed in the following steps
    I. $$Ca+2C\rightarrow CaC_2$$    50% yield
    II. $$CaC_2+N_2\rightarrow CaCN_2+C$$   100% yield
    III. $$CaCN_2+3H_2O\rightarrow 2NH_3+CaCO_3$$        50% yield
    To obtain 2 moles $$NH_3$$, calcium required is:
    Solution
    It can be easily observed from the reaction given that 1mole of Ca is required to get 2 moles of $$NH_3$$
  • Question 7
    1 / -0
    As per Braun's principle, yield of Ammonia will be more in Haber's process under ______, conditions ($$L=$$ Low; $$H=$$ high; $$T=$$ Temp; $$P=$$ Pressure)
    Solution
    The manufacture of $$NH_3$$ by Haber's process is given as
    $${ N }_{ 2 }(g)+{ 3H }_{ 2 }(g)\rightleftharpoons { 2NH }_{ 3 }(g)\\ \triangle 6H°=-92.4\\ $$
    so, it is an exothermic reversible reaction and occurs with decrease in volume.
    so, the low temperature will favour the forward reaction which is exothermic in nature
    and since the reaction occurs with a decrease in volume .so, high pressure will favour the formation of of$$NH_3$$.
  • Question 8
    1 / -0
    When two atoms of chlorine combine to form one molecule of chlorine gas, the energy of the molecule:
    Solution
    The energy of the molecule is less than that of a separate atom because the $$Cl_2$$ molecule is more stable than the $$Cl$$ atom.

     $$Cl$$ atom is more reactive and it has more energy and less stability. It combines with other $$Cl$$ atom to form $$Cl_2$$ which has less energy and more stability than an individual atom.

    Hence, option $$C$$ is correct.
  • Question 9
    1 / -0
    The role of zinc stearate in the process of vulcanisation is:
    Solution
    • In sulphur vulcanization of natural rubber excess zinc stearate enhances the yield of crosslinks, reduces their average length, and inhibits their destruction.
    • It is an "activator" for accelerated rubber sulfur vulcanization.
  • Question 10
    1 / -0
    Which of the following characteristics regarding 7 halogens is not correct? 
    Solution
    • Electron Affinity (decreases down the group) Since the atomic size increases down the group, electron affinity generally decreases (At < I < Br < F < Cl). An electron will not be as attracted to the nucleus, resulting in a low electron affinity
    • However, fluorine has a lower electron affinity than chlorine. Chlorine has higher electron gain enthalpy than fluorine because due to the small size of fluorine some energy is utilized in overcoming the force of repulsion among electrons.
    • Hence option C is an incorrect answer.
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