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Weekly Quiz Competition
  • Question 1
    1 / -0

    Which of the following statements is true:

    Solution

    N-N is weaker than P-P

    Other statements as incorrect as Phosphorus has a higher melting point due to bigger size than Nitrogen. Nitrogen is inert due to formation of triple bonds and has a lower covalence due to non - availability of d –orbitals.

  • Question 2
    1 / -0

    Which of the following is a non-stoichiometric defect?

    Solution

    Metal deficiency defect (anion is missing from lattice site)

    In Frenkel defect the smaller ion occupies the interstitial sites and Schottky defect equal number of cations and anions are missing. Interstitial defect an atom or molecule occupies intestinal sites so in these three defects the ratio of positive and negative ions (Stoichiometric) of a solid is not disturbed in these three.

  • Question 3
    1 / -0

    Identify the law which is stated as:

    “For any solution, the partial vapour pressure of each volatile component in the solution is directly proportional to its mole fraction.”

    Solution

    Raoult’s law - For any solution, the partial vapour pressure of each volatile component in the solution is directly proportional to its mole fraction.

    \(p\propto x\)

    \(p=p^\circ x\)

    where p = partial vapour pressure,

    \(p^\circ\) = Vapour pressure of pure component.

    x = mole fraction.

  • Question 4
    1 / -0

    Pink colour of LiCl crystals is due to:

    Solution

    Metal excess defect- It creates F-center in the crystal lattice which is due to a type of crystallographic defect in which an anionic vacancy in a crystal lattice is occupied by one or more unpaired electrons and that is responsible for the color.

  • Question 5
    1 / -0

    Which of the following isomer has the highest melting point:

    Solution

    1,4 dichlorobenzene - The melting points of this isomer will be high due to its symmetric structure and it will form most stable arrangement or we can say a good packing by these molecules can be formed. But other isomers have does not have symmetric nature which may cause little difficulty in the packing of each molecule.

    So, para isomer is more symmetric than ortho and meta.

  • Question 6
    1 / -0

    Which one of the following reactions is not explained by the open chain Structure of glucose:

    Solution

    Existence of alpha and beta forms of glucose.

  • Question 7
    1 / -0

    Williamson’s synthesis of preparing dimethyl ether is an:

    Solution

    \(S_N2\) reaction (Alkoxide ion reacts with primary alkyl halide in a single step to form ether).

  • Question 8
    1 / -0

    Chlorine water loses its yellow colour on standing because:

    Solution

    A mixture of HOCl and HCl is produced in the presence of sunlight \(Cl_2(g)+H_2O(l)\) \(\rightarrow HCl(g)+HOCl(aq).\)

  • Question 9
    1 / -0

    Amorphous solids are:

    Solution

    Amorphous solids are: isotropic

    (The value of any physical property is same along any direction).

  • Question 10
    1 / -0

    Which of the following is an example of a solid solution?

    Solution

    22 carat gold (It is an alloy so solid in solid solution).

  • Question 11
    1 / -0

    The boiling points of alcohols are higher than those of hydrocarbons of comparable masses due to:

    Solution

    Hydrogen bonding (Alcohols form intermolecular hydrogen bonds).

  • Question 12
    1 / -0

    Which of the following has the lowest boiling point:

    Solution

    \(H_2S\) (Boiling point increases down the group but water forms strong hydrogen bonds so has higher boiling point than \(H_2S).\)

  • Question 13
    1 / -0

    Which of the following statement is correct:

    Solution

    pH does not affect the primary structure of protein (pH effects the tertiary structure).

  • Question 14
    1 / -0

    Major product obtained on reaction of 3-Phenyl propene with HBr in presence of organic peroxide

    Solution

    1 – Phenyl -3 - bromopropane

    \(((C_6H_5)CH_2CH=CH_2+HBr\) (organic peroxide) \(\rightarrow(C_6H_5)CH_2CH_2CH_2Br\) anti-Markovnikov addition).

  • Question 15
    1 / -0

    Which of the following is a correct statement for \(C_2H_5Br?\)

    Solution

    It gives nitroethane on heating with aqueous solution of \(AgNO_2\)

    \((C_2H_5Br\) reacts with metallic Na to give butane, gives ethene on boiling with alcoholic potash. and forms \(C_2H_5SH\) (thiol) on heating with alcoholic KSH).

  • Question 16
    1 / -0

    Covalency of nitrogen is restricted to:

    Solution

    4 (Covalency of nitrogen is restricted to 4 due to non availability of d orbitals).

  • Question 17
    1 / -0

    Solubility of gases in liquids decreases with rise in temperature because dissolution is an:

    Solution

    Exothermic and reversible process (According to Le -Chatlier principle Solubility of gases in liquids decreases with rise in temperature).

  • Question 18
    1 / -0

    All elements of Group 15 show allotropy except:

    Solution

    Nitrogen (Due to small size and high electronegativity N-N is weak).

  • Question 19
    1 / -0

    Which of the following is a polysaccharide?

    Solution

    Glycogen (It is a polymer of glucose).

  • Question 20
    1 / -0

    Substance having the lowest boiling point:

    Solution

    Helium: (He is monoatomic and has low atomic mass)

    It belongs to Nobel gases group (group -18) and they have very least inter-atomic attraction due to which their boiling points are very low.

  • Question 21
    1 / -0

    Lower molecular mass alcohols are:

    Solution

    Miscible in water in all proportions Lower molecular mass alcohols are able to form hydrogen bonds with water.

  • Question 22
    1 / -0

    In which of the following cases blood cells will shrink:

    Solution

    When placed in water containing more than 0.9% (mass/ volume) NaCl solution because fluid inside blood cells is isotonic with 0.9% NaCl solution. When concentration of solute outside of the cell is increased then due to osmosis the solvent inside the cell come out thus blood cell get shrink.

  • Question 23
    1 / -0

    How much ethyl alcohol must be added to 1 litre of water so that the solution will freeze at \(–14^\circ C?\,(K_f\) for water \(=1.86^\circ C/mol)\)

    Solution

    7.5 mol

    \(\triangle T_f=K_f\,m\)

    \(\triangle T_f=K_f\,\frac{n_2\times1000}{w_1}\)

    \(14=1.86\times\frac{n_2\times1000}{1000}\)

    \(n_2=7.5\,mol.\)

  • Question 24
    1 / -0

    On partial hydrolysis, \(XeF_6\) gives:

    Solution

    \(XeO_2F_2+4HF\)

    \(XeF_4+H_2O\rightarrow XeO_2F_2+4HF\)

  • Question 25
    1 / -0

    Which one of the following statement is correct about sucrose :

    Solution

    It undergoes inversion in the configuration on hydrolysis. Initially sucrose is dextro but on hydrolysis it convert into laevo because hydrolysis product is glucose and fructose in which fructose has larger coefficient of laevorotation. This is why Sucrose go inversion in configuration on hydrolysis.

  • Question 26
    1 / -0

    Phenol does not undergo nucleophilic substitution reaction easily due to:

    Solution

    Partial double bond character of C-OH bond.

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