$$\begin{array}{l} Given\, in\, \, \, \Delta ABC, \\ \, \, \, \, \, \, \, \, \, \, \, \, 2\, \overrightarrow { AB } =3\overrightarrow { CB, } \\ \, \, \, \, \, \, \, \, \, \, \, \, 2\overrightarrow { OA } =3\overrightarrow { OB } , \\ We\, know\, that, \\ \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \overrightarrow { AC } =\overrightarrow { OC } \, -\overrightarrow { OA } \\ \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \overrightarrow { CB } =\overrightarrow { OB } -\overrightarrow { OC } \\ then, \\ \, \, \, 2(\overrightarrow { OC } -\overrightarrow { OA } )=3(\overrightarrow { OB } -\overrightarrow { OC } ) \\ 2\, \overrightarrow { OC } +2\overrightarrow { \, OA } =3\overrightarrow { OB } -3\overrightarrow { OC } \\ 2\, \, \overrightarrow { OC } -3\, \overrightarrow { \, OC } =3\, \overrightarrow { \, OB } +2\overrightarrow { OA } \\ 5\, \overrightarrow { OC } =\, \, 2\overrightarrow { OA } \, +3\, \overrightarrow { \, OB } \end{array}$$
$$\,So,\,\,\,\,2\overrightarrow {OA} \, + 3\,\overrightarrow {\,OB} = 5\,\overrightarrow {OC} $$