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Atoms Test - 43

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Atoms Test - 43
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  • Question 1
    1 / -0
    A singly ionized helium atom in an excited state $$\left( n=4 \right)$$ emits a photon of energy $$2.6 eV$$. Given that the ground state energy of hydrogen atom is $$-13.6 eV$$, the energy $$\left( { E }_{ f } \right) $$ and quantum number $$\left( n \right) $$ of the resulting state are respectively,
    Solution
    From the Bohr's theory of single electron species, we have the Energy of the state (quantum number = n) and atomic number = Z as
    $$E=-13.6\frac{Z^2}{n^2}$$

    Thus, Energy of $$4^{th}$$ state in Helium ion is $$E_4^{He^+} = -13.6\times \frac{2^2}{4^2}=-3.4eV$$

    Energy of the emitted photon is $$E_p = 2.6eV$$

    Energy after emitting the photon is $$E_f = E_4^{He^+}-E_p = -3.4-2.6=-6eV$$

    The quantum number is given by $$n = (\frac{-13.6\times Z^2}{E_n})^{\frac{1}{2}} = \sqrt{\frac{-13.6\times 4}{-6}}=\sqrt{9}=3$$
  • Question 2
    1 / -0
    The ionization energy of $${ Li }^{ 2+ }$$ is equal to
    Solution
    Ionization energy of an atom  $$=hc R{ Z }^{ 2 }$$
    where $$R$$ is the Rydberg constant and $$Z$$ is the atomic number.
    We know,  $$Z=3$$ for $${ Li }^{ 2+ }$$
    Ionization energy of $$Li^{2+}$$  $$={ \left( 3 \right)  }^{ 2 }hcR$$ $$=9 hcR$$
  • Question 3
    1 / -0
    An electron in hydrogen atom after absorbing an energy photon jumps from energy state $${n}_{1}$$ to $${n}_{2}$$. Then it returns to ground state after emitting six different wavelengths in emission spectrum. The energy of emitted photons is either equal to less than the absorbed photons. The $${n}_{1}$$ and $${n}_{2}$$ are
    Solution
    From $$n_2=4$$, 
    6 lines are obtained in emission spectrum.
    Now, $$E_{4-2}=E_{absorbed}$$
    $$F_{4-3}<E_{absorbed}$$
    and $$E_{4-1}, E_{3-1}, E_{2-1}>E_{absorbed}$$
    Hence, $$n_1=2$$ and $$n_2=4$$
  • Question 4
    1 / -0
    The transition from from the state $$n = 5$$ to $$n = 1$$ in a hydrogen atom results in $$UV$$ radiation. Infrared radiation will be obtained in the transition.
    Solution
    $$\dfrac{1}{\lambda}=R(\dfrac{1}{n_1^2}-\dfrac{1}{n_2^2})$$
    for UV $$n_1=1$$ and $$n_2=5$$, $$\lambda=\dfrac{1.04}{R}$$
    for infrared the wavelength must be greater the UV wavelength.
    For $$n_1=3$$ and $$n_2=4$$ , $$\lambda=\dfrac{7.2}{R}$$. This is the largest wavelength we can get  
  • Question 5
    1 / -0
    Light of wavelength $$ \lambda = 4000 A^o $$ and intensity $$ 100 W/m^2 $$ is incident on a plate the threshold frequency $$ 5.5 \times 10^{14} Hz. $$ Find the number of photons incident $$ m^2 $$ per sec.
    Solution
    Let number of photons emitted per second be $$ n. $$
    Then intensity $$ = 100 W/m^2 $$
    $$ \dfrac {nhc}{\lambda} = 100 $$
    $$ n = \dfrac {100 \times \lambda }{hc} $$
    $$ = \dfrac {100 \times 4000 \times 10^{-10}}{6.6 \times 10^{-34} \times 3 \times 10^8 } $$
    $$ = 2.02 \times 10^{20} $$
  • Question 6
    1 / -0
    A gas of monoatomic hydrogen is bombarded with a stream of electrons that have been accelerated from rest through a potential difference of $$12.75V$$. In the emission spectrum one cannot observe any line of
    Solution
    Energy of electron stream $$=12.75eV.$$
    The ground state electron having energy $$-13.6eV$$ will acquire this energy and have total energy $$=13.6+12.75=-0.85eV$$.
    This corresponds to the energy of electron in the 4th orbit. So, it will radiate energy when electron jumps from 4th orbit.
    Hence, Pfund series cannot be observed.
  • Question 7
    1 / -0
    The difference between a photon and neutrino is :
    Solution
    The spin of photons is 1 and that of neutrino is $$ \dfrac {1}{2} $$ in units of $$ \dfrac {h}{2 \pi} . $$
  • Question 8
    1 / -0
    In Bohr's theory of Hydrogen atom, the electron jumps from higher orbit 'n' to lower orbit 'p'. The wavelength will be minimum for the transition
    Solution
    Wavelength of light emitted due to transition from $$n$$ to $$p$$ orbits  $$\dfrac{1}{\lambda } = R \bigg(\dfrac{1}{p^2} - \dfrac{1}{n^2} \bigg)$$
    $$\implies$$ $$\lambda = \dfrac{n^2 p^2}{R(n^2 - p^2)}$$
    Case (A) :  $$n =5$$   $$p =4$$
    We get  $$\lambda_A = \dfrac{5^2 \times 4^2}{R(5^2 - 4^2)} = 44.44 R$$
    Case (B) :  $$n =4$$   $$p =3$$
    We get  $$\lambda_B = \dfrac{4^2 \times 3^2}{R(4^2 - 3^2)} = 20.57 R$$
    Case (C) :  $$n =3$$   $$p =2$$
    We get  $$\lambda_C = \dfrac{3^2 \times 2^2}{R(3^2 - 2^2)} = 7.2 R$$
    Case (D) :  $$n =2$$   $$p =1$$
    We get  $$\lambda_D = \dfrac{2^2 \times 1^2}{R(2^2 - 1^2)} = 1.33 R$$
    Thus minimum wavelength is emitted when a transition takes place from $$n=2$$ to $$p=1$$ orbit.
  • Question 9
    1 / -0
    Electrons are excited form $$n=1$$ to $$n=4$$ state. During downward transitions, possible number of spectral lines observed in Balmer series is.
    Solution
    For Balmer series it should move to n=2
    so possible line are $$n=4\rightarrow n=2$$ 
    $$n=3\rightarrow n=2$$ 
  • Question 10
    1 / -0
    An electron enters a parallel plate capacitor with horizontal speed $$\mu$$ and is found to deflect by angle $$\theta$$ on leaving the capacitor as shown. It is found that $$\tan\theta=0.4$$ and gravity is negligible. If the initial horizontal speed is doubled, then $$\tan$$ will be.

    Solution
    let the horizontal length of plate be L
    now $$t=L/\mu$$
    now $$v_y=at=\dfrac{eE}{m}\dfrac{L}{\mu}$$
    $$tan\theta=\dfrac{v_y}{\mu}=\dfrac{eEL}{m\mu^2}=0.4$$
    when speed becomes double 
    $$tan\theta=\dfrac{v_y}{\mu}=\dfrac{eEL}{m(2\mu^2)}=0.1$$
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