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Atoms Test - 51

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Atoms Test - 51
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  • Question 1
    1 / -0
    In an atom an electron excites to the fourth orbit. When it jumps back to the energy levels a spectrum is formed.Total number of spectral lines in this spectrum would be 
    Solution
    In an atom an electron excites to the fourth orbit, $$n=4$$
    The total number off spectral lines in the spectrum is,
    $$\dfrac{n(n-1)}{2}=\dfrac{4(4-1)}{2}=\dfrac{4\times 3}{2}=6$$
    The correct option is D.
  • Question 2
    1 / -0
    A proton, a direction ion and an $$\alpha$$-particle of equal kinetic energy perform circular motion normal to a uniform magnetic field $$B$$. If the radii of their paths are $$r_p, r_d$$ and $$r_\alpha$$ respectively then [Here, $$q_d = q_p, m_d = 2m_p$$]
    Solution
    $$\begin{array}{l}\text { Given, } \\\text { a proton } \quad q=+1 \quad m=m_p \\\text { a deutorium } \quad q=+ 1 \quad m=2 \mathrm{m_p} \\\text { a } \alpha \text { particle }\quad q=+ 2 \quad m=4 \mathrm{m_p} \end{array}$$
    $$\begin{array}{l}\text { hane equal Kinctic energy } \\\qquad B=\text { magnetic field. }\end{array}$$
    $$\begin{array}{l}\text { We Know when a change particle enters } \\\text { in a magnetic field it perform } \\\text { circular motion with radius equal to. }\end{array}$$
    $$\begin{aligned}r &=\frac{m v}{q B} \\r &=\frac{\sqrt{2 m K E}}{q B}\end{aligned}$$
    $$\begin{array}{l}r_{\text {proton }}=\frac{\sqrt{2 \times m_p \times K E}}{1\times B} \\\text r_{ deutorium }=\frac{\sqrt{2 \times 2 \times m_p \times K E}}{1 \times B}\\\text r_{\alpha }=\frac{\sqrt{2 \times 4 \times m_p\times K E}}{2 \times B}=\frac{\sqrt{2 \times m_p \times K E}}{1 \times B}\end{array}$$
    $$\text { So, } \quad r_{\text {proton }}=r_{\alpha} < r_{\text {deutorium }}(\text {option } B)$$
  • Question 3
    1 / -0
    If radiation of all wavelengths from ultraviolet to infrared is passed through hydrogen gas at room  temperature absorption lines will be observed in the 
    Solution
    $$\begin{array}{l}\text { For hydrogen atom only one electron is } \\\text { present at ground state. when it absorb } \\\text { energy of different wavelength, it transist } \\\text { from } n=1 \text { to } n=2,3,4 \text { and so on, } \\ \text{so, only lymen series id obsererved due to}\\\text { absence of electron on other energy level. }\end{array}$$
  • Question 4
    1 / -0
    The radius of first orbit of hydrogen atom is $$0.53\ A$$. The radius of its fourth orbit will be-
    Solution
    $$\text{Given- $*$ Radius of first orbit=0.53 A}$$
    $$\text{We know that -}$$
    $$\text{Radius of the orbit of $e^{-}(r),$}$$
    $$\text { r } \alpha  n^{2} ,\quad n \rightarrow n^{\text {th }}orbit$$
    $$\Rightarrow \frac{r_{1}}{r_{2}}=\frac{n_{1}^{2}}{n_{2}^{2}}\quad\text { Let } r_{2} \text { be the radius of } 4^{\text {th }} \text { orbit }$$
    $$\Rightarrow \quad r_{2}=\frac{n_{2}^{2}}{n_{1}^{2}} \cdot r_{1}$$

    $$\begin{array}{l}\text { for } 4^{\text {th }} \text { orbit, }n_{2}=4\text { and } n_{1}=1 \\\Rightarrow \quad r_{2}=(4)^{2} \cdot r_{1}=16 \times 0.53 A^{\circ} \\\Rightarrow r_{2}=8.48 A^{\circ}\\\text { Hence, option (D) is correct. }\end{array}$$
  • Question 5
    1 / -0
    If in Bohr's atomic model, it is assumed that force between electron the proton varies inversely as $${r^4},$$b energy of the system will be proportional to:
    Solution
    $$\dfrac{mv^2}{r}=\dfrac{k}{r^4}$$
    $$V^2=\dfrac{k}{mr^3}$$
    we know
    $$mvr=\dfrac {nh}{2x}$$
    $$m^2v^2r^2=\dfrac{n^2h^2}{4\pi^2}$$
    $$\dfrac{m^2kr^2}{mr^3}=\dfrac{n^2h^2}{4x^2}$$
    $$r=\dfrac{mk4\pi^2}{n^2h^2}$$
    $$k.f$$=$$\dfrac{1}{2}mv^2=\dfrac{1}{2}m/\dfrac{k}{mr^3}$$
    $$=\dfrac{1}{2}m\dfrac{K}{m^1m^3}$$
    $$E\alpha\ n^6$$
  • Question 6
    1 / -0
    If m is mass of electron, v its velocity, r the radius of stationary circular orbit around a nucleus with charge Ze then from Bohr's first postulate, the kinetic energy $$K=\dfrac{1}{2}mv^2$$ of the electron in C.G.S. system is equal to?
    Solution
    In the revolution of an electron, coulomb force provides the necessary centripetal force

    $$\Rightarrow \dfrac{ze^{2}}{r^{2}}=\dfrac{mv^{2}}{r}\Rightarrow mv^{2}=\dfrac{ze^{2}}{r}$$

    $$\therefore K.E. \dfrac{1}{2}mv^2=\dfrac{Ze^2}{2r}$$

  • Question 7
    1 / -0
    A Proton and an $$/alpha $$ particle are accelerated through a potential difference of 100V. The ratio of the wavelength associated with the proton to that associated with an $$/alpha $$ particle is
    Solution
    $$Enrgy=\dfrac{Momentum^2}{2m}=p^2/2m$$
    So momentum $$p=\sqrt[2]{2mE}$$, $$m$$ is mass.
    Wavelength$$\lambda=\dfrac{h}{p} i.e$$ $$ \lambda \propto \dfrac{1}{p}$$
    So required ratio is $$\sqrt[2]{\dfrac{m_aE_a}{m_pE_p}}$$

    Mass of alpha particle is $$m_a=4m$$ where $$m=m_p$$ is mass of proton.
    Energy of alpha particle $$E_a=q_aV=2e\times100$$
    and energy of proton is $$E_p=q_pV=e\times100$$
    Putting all the values we get the ratio as $$\sqrt[2]{\dfrac{800me}{100me}}=\dfrac{2\sqrt[2]{2}}{1}$$
  • Question 8
    1 / -0
    Electrons accelerated from rest by a potential difference of $$12.75V$$, are bombarded on a mono-atomic hydrogen gas. Possible emission of spectral lines are:-
    Solution
    $$ \begin{array}{l} \text { when it get energy of } 12.75 \text { ev it  excited to } \\ n=4 \quad E_{4}-E_{1}=12.75 \mathrm{ev} \end{array} $$ 
    $$ \begin{array}{l} \text { then after it comes down, possible emission will } \\ \text { be } \end{array} $$ 
    $$ \begin{array}{l} \text { Line fall on } n=1 \text { ane lyman line }=3 \\ \text { Line fall on } n=2 \text { are balmer line }=2 \\ \text { Line fall on } n=3 \text { are paschen line }=1 \end{array} $$

  • Question 9
    1 / -0
    A positroniuim  consists of an electron and a positron revolving about their common centre of mass. Calculate the kinetic energy of the electron in ground state:
    Solution
    $$E_k \propto m$$
    Where $$m$$ is reduced mass of electron in the orbit.
    For hydrogen atom $$m=\dfrac{m_em_p}{m_p +m_e}$$ which is $$m_e$$  .......(1)   
     because mass of proton $$m_p$$ is much larger
     than the mass of electron $$m_e$$.
    Mass  of positron is equal to mass of electron so reduced mass of electron
    for this pair will be $$m=m_e^2/2m_e=m_e/2$$ ..............(2)
    As energy for hydrogen atom is $$13.6eV$$ 
    so energy for electron-positron pair will be $$13.6/2=6.8eV$$ 
    Because in this case  reduced mass is $$m_e/2$$ i.e. half of that in the case of hydrogen atom.(See equation-2 and equation-1)
    Option C is correct.
  • Question 10
    1 / -0
    The ground state energy of $$H$$- atom is $$-13.6eV$$. The energy needed to ionise $$H$$- atoms from its second excited state is:
    Solution
    The energy  of $$n^{th}$$ state in the hydrogen state will be $$E_n=-\dfrac{13.6eV}{n^2}$$
    so this energy for the second $$excited $$ state i.e. $$n=3$$ will be $$E_3=\dfrac{-13.6eV}{9}=-1.51ev$$
    So ionization energy for this state will be $$-(-1.51eV)=1.51eV$$
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