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Atoms Test - 55

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Atoms Test - 55
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  • Question 1
    1 / -0
    The figure indicates the energy level diagram of an atoms and the origin of six spectrum lines in emission (e.g line no.$$5$$ arises from the transition from level $$B$$ to $$A$$) Which of the following spectral lines will occur in the absorption spectrum?

    Solution
    The absorption lines are obtained when the electron jumps from ground state $$(n = 1)$$ to the higher energy states. Thus only $$1, 2$$ and $$3$$ lines will be obtained.
  • Question 2
    1 / -0
    Find the frequency of revolution of the electron in the first stationary orbit of H-atom 
    Solution
    $$frame=\dfrac{1}{Time\  period}$$
    Time perid$$=\dfrac{Total \ distance \ coverd}{velocity}=\dfrac{2\pi r}{v}$$
    frequency$$=\dfrac{v}{2\pi r}$$
    The velocity $$v_2$$ and radius $$r_2$$ of the $$2^{nd}$$ both orbit
    $$ r_n=(0.53\times 10^{-10}n^2/Z)\ m$$ , $$Z=1\ and\  n=2 $$
    $$r_2=0.53\times10^{-10}(2^2)\ =2.12\times 10^{-10}m$$
    $$v_n=2.165\times 10^{6}\left(2/n\right)m/s$$
    $$v_2=2.165\times 10^{6}\left(1/2 \right)=1.082\times 10^6m/s$$
    frequency$$=\dfrac{v_2}{2\pi r_2}=\dfrac{1.082\times 10^6}{2(x)(2.12\times 10^{-10})}$$
    $$f=8.13\times 10^{16}Hz$$
  • Question 3
    1 / -0
    In hydrogen atom, the electron is making $$6.6\times 10^{15}rev/s$$ around the nucleus in an orbit of radius $$0.528A^0$$. The equivalent magnetic dipole moment is :
    Solution

  • Question 4
    1 / -0
    What will be relation between first bohr radius of H- atom and D-atom
    Solution

  • Question 5
    1 / -0
    The Bohr radius of the fifth electron of phosphorus (atomic number = 15) acting as dopant in silicon (relative dielectric constant = 12) is 
    Solution
    $${r_n} = { \in _r}\left( {\frac{{{n^2}}}{Z}} \right)$$
    $${a_0} = 12 \times \frac{{{{\left( 5 \right)}^2}}}{{15}} \times 0.53 = 10.6\mathop A\limits^0 $$
    Hence,
    option $$(A)$$ is correct answer.
  • Question 6
    1 / -0
    The radius of the orbit of an electron in a Hydrogen-like atom is $$3{ a }_{ 0 }$$, where $${ a }_{ 0 }$$ is the Bohr radius. Its orbital angular momentum is $$\frac { 3h }{ 2\pi  } $$. It is given that h is Planck's constant and R is Rydberg constant. The possible wavelength, when the atom de-excites is :
    Solution
    solution:
    given ;
    $$4.5a_0 = a_0 \dfrac{n^2}{Z}----(i)$$
    $$\dfrac{nh}{2\pi} = \dfrac{3h}{2\pi} ----(ii)$$

    so , n= 3 and z=2
    so , possible wavelength are:

    $$\dfrac{1}{\lambda _1}= RZ^2[\dfrac{1}{1^2} - \dfrac{1}{3^2}] \Rightarrow \lambda _1= \dfrac{9}{32R}$$

    hence the correct option:D
  • Question 7
    1 / -0
    What is the ratio of the shortest wavelength of the Balmer series to the shortest wavelength of the Lyman series ?
    Solution
    For transition $$n_2 \rightarrow n_1$$
    the wavelength is given by $$\dfrac{1}{\lambda}=RZ^2(\dfrac{1}{n_1^2}-\dfrac{1}{n_2^2})$$
    For shortest wavelength in Lyman series put $$n_1=1$$ and $$n_2 \rightarrow \infty$$
    and for shortest wavelength in Balmer series put $$n_1=2$$ and $$n_2 \rightarrow \infty$$
    we get  $$\dfrac{1}{\lambda _L}=RZ^2$$
    and  $$\dfrac{1}{\lambda _B}=RZ^2(\dfrac{1}{4})$$
    ratio will be  $$\dfrac{\lambda _B}{\lambda _L}=\dfrac{4}{1}$$

    Option A is correct.
  • Question 8
    1 / -0
    The number of bond pair of electrons and lone pair of electrons in $$O_2$$ molecules respectively are
    Solution

  • Question 9
    1 / -0

    In a cubical vessel $$1m \times 1m\times 1m$$ the gas molecules of diameter $$1.7 \times {10^{ - 8}}\;{\text{cm}}$$ are at a temperature 300 K and a pressure of $${10^{ - 4}}\;{\text{mm}}$$ mercury. The mean free path of the gas molecule is 

    Solution
    The mean free path or average distance between collison for a gas molecule may be estimated from KTG(Kinetic Theory of Gases).
    From Serway's approach:-
    $$(Mean\quad free\quad path)\lambda=\cfrac{1}{\pi d^2n_v}$$
    $$d\rightarrow $$ diameter of molecule
    $$n_v\rightarrow$$ No. of molecules per unit volume
    From idle gas law,
    $$n_v=\cfrac{nN_A}{V}\Rightarrow n_v=\cfrac{N_AP}{RT}$$
    So, from $$(i)$$
    $$\lambda=\cfrac{RT}{\sqrt{2}\pi d^2N_A P}$$
    A/Q we have
    $$d=1.7\times 10^{-8}cm=17\times10^{-10}m\\P=10^{-4}mmHg\\T=300K\\ \lambda=\cfrac{8.314\times 300}{\sqrt2 \times3.14\times (1.7\times10^{-10})^2}(6.022\times10^{23}(10^{-4}))\\ \quad=\cfrac{8.314\times 3\times10^3}{1.414\times3.14\times2.89\times6.022}\\ \quad=2.4201m$$
  • Question 10
    1 / -0
    Suppose that the potential energy of a hypothetical atom consisting of a proton and an electron is given by U = - Ke$$^{2}$$ / 3 r$$^{3}$$.Then if Bhor's postulates are applied to this atom ,then the radius of the n $$^{th}$$ orbit will be proportional to:
    Solution
    $$u = \frac{{ - k{e^2}}}{{2{r^3}}}$$
    $$F = \frac{{ - du}}{{dr}}$$
    $$ = \frac{{k{e^2}}}{{{r^2}}}$$
    $$\frac{{k{e^2}}}{{{r^2}}} = \frac{{m{v^2}}}{r}$$---------------$$(1)$$
    $$mvr = \frac{{nh}}{{2\pi }}$$---------------$$(2)$$
    $$ \Rightarrow r\alpha {n^2}$$
    Hence,
    option $$(A)$$ is correct answer.
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