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Atoms and Molecules Test - 70

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Atoms and Molecules Test - 70
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  • Question 1
    1 / -0
    How many moles of magnesium phosphate, $$Mg_3(PO_4)_2$$ will contain 0.25 mole of oxygen atoms ? 
    Solution
    $$1$$ molecule of $$Mg_3(PO_4)_2$$ has $$8$$ atoms of Oxygen.

    $$\Rightarrow 1$$ mole of $$Mg_3(PO_4)_2$$ has $$8$$ mole of Oxygen atoms.

    Now, it is given $$0.25$$ mole of oxygen atoms
    $$\therefore$$ Moles of $$Mg_3(PO_4)_2$$ having $$0.25$$ mole of $$O$$ atoms is $$\cfrac {0.25\times 1}{8}$$ moles
    $$=0.03125$$ moles

    $$=3.125\times 10^{-2}$$ moles

    Hence, option B is correct.
  • Question 2
    1 / -0
    Number of atoms in 558.5 g of Fe:

    (Atomic mass of Fe = 55.85 u)
    Solution
    Given mass of Fe = $$ 558.5\ g$$

    Molar mass of Fe = $$ 55.85\ g/mol$$ (As we know that atomic mass and molar mass are numerically equal, only units change, and the atomic mass is given in question)

    No. of moles of Fe = $$\dfrac {Given\ mass}{Molar\ mass}$$ = $$\dfrac {558.5}{55.85}$$ = $$10\ moles$$ 

    Hence, no. of atoms in 10 moles of Fe = $$ 10 \times Avogadro\ number$$ = $$10 \times 6.023 \times 10^{23}$$ = $$6.023 \times 10^{24}\ atoms$$
  • Question 3
    1 / -0

    The ratio of unpaired electrons present in d orbitals of $$Co^{2+}$$ and $$Cr^{3+}$$Co2+ is ____.
    Solution
    Ground state configuration of cobalt
    $$=[Ar]3d^74s^2$$
    Ground state configuration of $${ Co }^{ 2+ }$$
    Remove $$2$$ electrons
    So only one unpaired $${ e }^{ - }$$
    Ground configuration of $$Cr=4{ s }^{ 1 }3{ d }^{ 5 }\\ { Cr }^{ 3+ }=4{ s }^{ 1 }3{ d }^{ 2 }$$
    unpaired electrons $$=3$$
    $$\boxed { { Co }^{ 2+ }:{ Cr }^{ 3+ }=1:3 } $$
  • Question 4
    1 / -0
    Specific volume of cylindrical virus particles is $${ 6.02\quad \times  }{ 10 }^{ -2 }$$ cc/gm whose radius and length are 7 $$\mathring A$$ and 10 $$\mathring A$$, respectively. If $${ N }_{ A }=6.02\times\  { 10 }^{ 23 }$$ find molecular weight of virus.
    Solution
    Solution:- (A) $$15.4 \; {Kg}/{mol}$$

    Volume of cylinder $$= \pi {r}^{2}h$$

    As the virus is cylindrical.

    $$\therefore$$ Volume of one virus $$=$$ volume of cylinder

    As the radius and length of virus are $$7 \mathring{A}$$ and $$10 \mathring{A}$$ respectively.

    $$\therefore$$ Volume of $$1$$ virus $$= \cfrac{22}{7} \times {7}^{2} \times 10 = 1540 \times {10}^{-24} {cm}^{3} = 1.54 \times {10}^{-21} {cm}^{3}$$        $$[\because \mathring 1 = 10^{-8} cm^3]$$

    Volume of $$1$$ mole of virus $$= {N}_{A} \times $$volume of $$1$$ virus

    $$\Rightarrow$$ Volume of $$1$$ mole of virus $$= 6.02 \times {10}^{23} \times 1.54 \times {10}^{-21} = 6.02 \times 1.54 \times {10}^{2} {cm}^{3}$$

    Given that specific volume of virus is $$6.02 \times {10}^{-2} {{cm}^{3}}/{g}$$

    $$\therefore \text{Molecular weight} = \cfrac{\text{volume of 1 mole}}{\text{Specific volume}} = \cfrac{6.02 \times 1.54 \times {10}^{2}}{6.02 \times {10}^{-2}} = 1.54 \times {10}^{4} \; {g}/{mol} = 15.4 \; {Kg}/{mol}$$

    Hence, the correct option is A.  
  • Question 5
    1 / -0
    If 10$$^{21}$$ molecules are removed from 200 mg of CO$$_{2}$$, the number of moles of CO$$_{2}$$ left is :
    Solution
    Answer:-
    Molar mass of $$C{O}_{2}$$ = 44g

    Given mass = 200 mg = 0.2g

    Number of moles = $$\cfrac{0.2}{44} = \cfrac{1}{220}$$

    $$\text{Number of moles} = \cfrac{\text{number of molecules}}{\text{Avogadro's number}}$$

    $$\Rightarrow \text{Number of molecules} = \text{Avogadro's number} \times \text{number of moles}$$

    $$\Rightarrow \text{No. of molecules} = 6.022 \times {10}^{23} \times \cfrac{1}{220} = 2.73 \times {10}^{21} \text{ Molecules in } \cfrac{1}{220} moles$$

    As $${10}^{21}$$ molecules  are removed,
    $$\therefore$$ No. of molecules left = $$2.73 \times {10}^{21} - {10}^{21} = 1.73 \times {10}^{21}$$

    $$\therefore \text{ No. of moles} = \cfrac{\text{No. of molecules}}{\text{Avogadro's number}} = \cfrac{1.73 \times {10}^{21}}{6.23 \times {10}^{23}} $$

                                 $$= 2.88 \times {10}^{-3}$$

    Hence, option $$A$$ is correct.
  • Question 6
    1 / -0
    If we assume that one-sixth the mass of an atom of $$^{12}C$$ isotope is taken as the reference, the mass of one molecule of oxygen will:
    Solution

    We know that $$12\ g\ of\ Carbon=6.023\times \ 10^{23} atoms$$

    So $$1\ g=\frac{6.023\ X\ 10^{23}}{12}$$

    $$6\ g\ of \ carbon=6\times \frac{6.023\ X\ 10^{23}}{12}$$

    or

    $$=\frac{1}{2}\times 6.023\ \times 10^{23}$$

    This is our new Avogadro's number according to the given conditions.

    Or

     $$1\ atomic\ mass\ unit=\frac{1}{N_A}=\frac{2}{6.023\ X\ 10^{23}}$$

    Mass of $$1$$ mole of $$O_2=32\times \ Avogrado's\ number\times \frac{2}{6.023\ \times 10^{23}}$$

    $$=32\times \frac{6.023\ \times 10^{23}}{2}\times \frac{2}{6.023\ \times 10^{23}}$$

    $$=32g$$

    Hence, there is no change in the mass number of $$O_2.$$

    Option $$\text{C}$$ is correct.

  • Question 7
    1 / -0
    How many oxygen atoms will be present in $$88\  g$$ of $$CO_2$$?
    Solution
    1 mol of $$CO_2=12+32=44\ g$$
    Number of oxygen in 1 molecule of $$CO_2=2$$

    $$\therefore$$ 44 g $$CO_2$$ contains 2 mol oxygen

    $$88\  g \ CO_2$$ contains $$=\cfrac{2}{44} \times 88=4$$ mol oxygen

    as, $$1 \ mol =6.022 \times 10^{23}$$ atoms

    $$4\  mol\  oxygen =4 \times 6.022 \times 10^{23}$$ oxygen atoms

    $$=24.08 \times 10^{23}$$ oxtgen atoms

    Hence, option $$A$$ is correct.
  • Question 8
    1 / -0
    How many grams of $$CaO$$ are required to react with $$852\ g$$ of $$P_4O_{10}$$ according to below given reaction:
    $$6CaO+P_4O_{10}\to 2Ca_3(PO_4)_2$$
    Solution
    The balanced reaction is : 
    $$6CaO + P_4O_{10} \rightarrow 2Ca_3 (PO_4)_2$$

    Molar mass of $$P_4O_{10}=4 \times 31 + 10 \times 16=284$$ g

    Moles of $$P_4O_{10} =\frac{mass}{molar\ mass}=\frac{ 852 }{284} = 3$$ moles

    1 mol of $$P_4O_{10}$$ react with 6 mol of $$CaO$$
    3 moles will react with$$= 3 \times 6 = 18$$ mol of $$CaO$$
    Mass of 1 mol of $$CaO=40+16=56$$ g
    Mass of 18 moles of $$CaO= 18 \times 56 = 1008$$ g
    option B is correct.
  • Question 9
    1 / -0
    P and Q are two elements which form $${ P }_{ 2 }{ Q }_{ 3 }$$ and $${ PQ }_{ 2 }$$. If 0.15 mole of $${ P }_{ 2 }{ Q }_{ 3 }$$ weight 15.9 g and 0.15mole of $${ PQ }_{ 2 }$$ weight 9.3 g. what are atomic weights of P and Q respectively?
    Solution
    Using- no. of mole $$=\cfrac{\text {weight}}{\text{molecular weight}}$$

    $$P_2Q_3 \Rightarrow $$ $$2P + 3Q =15.9/0.15= 106$$....(1)

    $$PQ_2 \Rightarrow $$ $$P + 2Q = 9.3/0.15=62$$........(2)

     On solving eqn. (1) & (2) we get- 

    $$P =26, Q = 18$$
  • Question 10
    1 / -0
    Who first gave the concept of 'atom'?
    Solution

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