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Chemical Equili...

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  • Question 1
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    An amount of solid \(\mathrm{N} \mathrm{H}_{4} \mathrm{HS}\) is placed in a flask already containing ammonia gas at a certain temperature and \(0.50\) atm pressure Ammonium hydrogen sulphide decomposes to yield \(\mathrm{N} \mathrm{H}_{3}\) and \(\mathrm{H}_{2} \mathrm{~S}\) gases in the flask. When the decomposition reaction reaches equilibrium, the total pressure in the flask rises to \(0.84\) atm. The equilibrium constant for \(\mathrm{NH}_{4}\) HS decomposition at this temperature is:

  • Question 2
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    H2O(l) ⇌ H2O (vap). This equation best illustrates the

  • Question 3
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    The mass of a gas dissolved in a given mass of a solvent at any temperature is proportional to the pressure of the gas above the solvent.

  • Question 4
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    The Bronsted acid which gives the weakest conjugate base is

  • Question 5
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    In the dynamic equilibrium stage, one of the following events take place. Choose the right one.

  • Question 6
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    The dynamic nature of chemical equilibrium can be demonstrated in the synthesis of ammonia by Haber.s process. Choose the appropriate option given below

  • Question 7
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    The factor that does not affect the state of equilibrium is 

  • Question 8
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    When the rate of evaporation is equal to the rate of condensation, it is called

  • Question 9
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    pKa values of four acids are given below at 25°C. Indicate the strongest acid.

  • Question 10
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    Which of the following represent(s) conjugate(s) of NH3?

  • Question 11
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    pH of an acid buffer is given by

  • Question 12
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    The equilibrium constant Kp for thermal dissociation of PCl5 at 200oC is 1.6 atm. The pressure (in atm) at which it is 50% dissociated at the same temperature is

  • Question 13
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    A solution which resists the change in its pH value on addition of some amount of acid or base is called

  • Question 14
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    In the reaction 3A + 2B  2C, the equilibrium constant Kis given by

  • Question 15
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    Which one of the following is not a Lewis base?

  • Question 16
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    The equilibrium constant for the reaction 2NO2 (g)  2NO (g) + O2 (g) is 2  10-6. The equilibrium constant for the reaction 4NO(g) + 2O2 (g) 4NO(g) at the same temperature would be

  • Question 17
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    For the reaction, H2(g) + I2(g) 2HI (g), the value of Kp changes with

  • Question 18
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    When aqueous solutions of two acids have the same concentration of common ions, they are called 

  • Question 19
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    Which of the following changes will shift the given reaction towards the product?

    l2 (g) ⇌ 2l (g), (298 K) = +150 kJ

  • Question 20
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    In which of the following solvents does AgBr have the greatest solubility?

  • Question 21
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    the rates of transfer of molecules from ice into water and of reverse transfer from water into ice are equal at atmospheric pressure and 273 K. Both the processes occur simultaneously and at the same rate so that the amount of ice and water remains constant. This process is called

  • Question 22
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    The boiling point of water at atmospheric pressure

  • Question 23
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    A solution of equal pH and pOH is called a

  • Question 24
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    During the process of transformation from liquid to vapour, the pressure exerted by the water molecules at a given temperature remains constant. This is called

  • Question 25
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    What is the equilibrium expression for the reaction P4 (s) + 5O2 (g)  P4O10 (s)?

  • Question 26
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    One mole of a compound AB reacts with one mole of a compound CD according to the equation AB + CD AD + CB. When equilibrium was established, it was found that 3/4 mol each of reactants AB and CD had been converted to AD and CB, respectively. There was no change in volume. The equilibrium constant for the reaction is

  • Question 27
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    If we place solid iodine in a closed vessel, after sometime the vessel gets filled up with violet vapour. When equilibrium is attained, the intensity of colour will be

  • Question 28
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    In the reaction 2O3 ⇄ 3O2, the value of Kc is 

  • Question 29
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    The solubility of CO2 in water increases with

  • Question 30
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    When the soda bottle is opened, some of the dissolved carbon dioxide gas escapes because of

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