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Classification of Elements and Periodicity in Properties Test - 6

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Classification of Elements and Periodicity in Properties Test - 6
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  • Question 1
    1 / -0

    Ionization enthalpy increases across a period because

    Solution

    Consider moving from lithium to fluorine across the second period, where successive electrons are added to orbitals in the same principal quantum level. The shielding of the nuclear charge by the inner core of electrons does not increase very much to compensate for the increased attraction of the electron to the nucleus. Thus, across a period, increasing nuclear charge outweighs the shielding. Consequently, the outermost electrons are held more and more tightly and the ionization enthalpy increases across a period.

  • Question 2
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    One of the following has ns1 as its outermost electronic configuration

    Solution

    The elements of Group 1 (alkali metals)  which have ns1 outermost electronic configuration belong to the s-Block Elements.

  • Question 3
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    The correct increasing order of radii of following species is  ----?

    Solution

    It is because

    (i)  radius  of anion  ( anionic radius ) is greater  , and
    (ii)  radius of  cation ( cationic radius ) is lesser than that of its parent neutral atom.

  • Question 4
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    Amongst the following elements (whose electronic configurations are given below), the one having the highest ionization enthalpy is
  • Question 5
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    To which block of elements in the periodic table 3d104s2 belongs?

    Solution

    d-block element have the general outermost electronic configuration as (n-1)d1-10 ns0-2.

  • Question 6
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    The ionisation enthalpy of lithium is 520 kJ/mol. How much enthalpy is needed to convert all atoms of Li to Li+ ions present in 7 mg of Li vapours?
  • Question 7
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    In the periodic table Electronegativity generally

    Solution

    The electronegativity value increases as the effective nuclear charge on the atomic nucleus increases. In a period moving from left to right, the electronegativity increases due to decrease in atomic radii resulting an increase in effective nuclear charge. Whereas, in a group moving from top to bottom, the electronegativity decreases because atomic radius increases due to subsequent addiiton of shells. 

  • Question 8
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    Which of the following is a set of isoelectronic species (At. No. of Cs = 55, Br = 35)?
  • Question 9
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    The elements with atomic numbers 9, 17, 35, 53 and 85 are all
  • Question 10
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    Identify the correct order in which the ionic radii of the following ions increase:

    I. F-
    II. Na+
    III. N3-
  • Question 11
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    The correct order of decreasing electronegativity values among the elements I - beryllium, II - oxygen, III - nitrogen and IV - magnesium is
  • Question 12
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    Consider the ions K+, S2-, Cl- and Ca2+. The radii of these ionic species follow which of the following orders?
  • Question 13
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    The correct order of increasing radii of the elements Na, Rb, K and Mg is
  • Question 14
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    The correct order of increasing radii of the elements Na, Si, Al and P is
  • Question 15
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    The polarizing power of the anions N3-, O2- and F-, follows the order
  • Question 16
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    Which of the following orders is not correct according to the property written against it?
  • Question 17
    1 / -0
    The ionization enthalpy of nitrogen is more than that of oxygen because of
  • Question 18
    1 / -0
    Column I Column II
    (a) He (i) High negative electron gain enthalpy
    (b) Cl (ii) Most electropositive element
    (c) Ca (iii) Strongest reducing agent
    (d) Li (iv) Highest ionisation enthalpy

    The correct match of the contents in column I with those in column II is
  • Question 19
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    Which of the following statements is/are correct?
  • Question 20
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    Which of the following isoelectronic ions has the lowest ionization energy?
  • Question 21
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    The correct order for the increase in atomic radii is

    Solution

    In a group movig from top to bottom the number of shells increases. So the atomic size increases. Although the effective nuclear charge increases but its effect is negligible in comparison to the effect of increasing number of shells.

  • Question 22
    1 / -0

    The correct order for the decrease in atomic radii is

    Solution

    In a period moving from left to right, the effective nuclear charge increases because the next electron fills in the same shell. So the atomic size decreases.

  • Question 23
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    Choose one of the following in the increasing order of electron gain enthalpy

    Solution

    In general as the we move down the group electron gain enthalpy decreases; so the expected trend should be I < Br < Cl < F  but in actual the order is I < Br < F < Cl . This is due to small size of F atom. The valence electrons of F atom provide strong repulsion to incoming electron, hence F has unexpectedly low electron affinity.

  • Question 24
    1 / -0
    The formation of oxide ion O2- (g) requires first an exothermic and then an endothermic step as shown below:

    O (g) + e-  O- (g)     Ho = - 142 kJ/mol
    O- + e-  O2- (g)    Ho = + 844 kJ/mol

    This is because
  • Question 25
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    Right order of increasing metallic character is:

    Solution

    Elements of s block are more matallic than p block elements

  • Question 26
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    In which of the following pairs is the first atom or ion not larger than the second?
  • Question 27
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    Which of the following electronic configurations corresponds to the element with the largest negative electron gain enthalpy?
  • Question 28
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    One of the following options is not used for explaining atomic radius

    Solution

    The distance from centre of the nucleus to the outermost shell containing the electrons is called atomic radius. There are four types that are widely used: covalent radii, metallic radii, van der Waal's radii and ionic radii.

  • Question 29
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    For P3-, S2- and Cl- ions, the increasing order of size is
  • Question 30
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    Directions: The following question has four choices out of which ONLY ONE is correct.

    Which of the following processes requires the highest energy?
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