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first law of thermodynamics is a restatement of
It is restatement of law of conservation of energy.It states that Thermodynamics isthe branch of physical science that deals with the relations between heat and other forms of energy (such as mechanical, electrical, or chemical energy), and, by extension, of the relationships between all forms of energy.
Calorimetry is an experimental technique or process of
Calorimetry is an experimental technique or process of measuring the heat of chemical reactions or physical changes as well as heat capacity.
In a closed system, Which of the following take place ?
In a closed system, there is no flow of matter from system to surrounding or vice versa.For example, a certain quantity of fluid bounded within a closed cylinder constitutes a closed system.
Standard enthalpy of fusion or molar enthalpy of fusion is
Molar enthalpy of fusion (always increases i.e. △H= positive) is the amount of energy needed to change completely one mole of a substance from the solid phase to the liquid phase in standard state.
Thermodynamics is the branch of physical science concerned with
Thermodynamics deals with heat and its transformation from one form to another.The branch of physical science that deals with the relations between heat and other forms of energy (such as mechanical, electrical, or chemical energy), and, by extension, of the relationships between all forms of energy.
In an open system, which if the following take place ?
In open system there is flow of matter and energy in and out of the system or vice versa.For example, an air compressor in which the air enters at a low pressure and exit at high pressure and there is energy interaction with the surrounding
The relationship between Cp and Cv for one mole of an
For a mole of ideal gas, The difference between Cp and Cv is always constant i.e. equals to gas constant.
Therefore, for one mole of an ideal gas, Cp- CV = R
According to first law of thermodynamics ΔU = q + w, here what is sign of q and w ?
The first law is simply a conservation of energy equation. q is positive if heat is added to the system, and negative if heat is removed; w is positive if work is done on the system, and negative if work is done by the system.
The molar specific heat capacity of a substance is the
Molar specific heat capacity can be defined as the amount of heat energy required to raise the temperature of 1 mole of a substance by 1° C.
An exothermic process
Exothermic process results in decrease in enthalpy of system hence for exothermic reaction ΔH= -ve.
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