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Thermodynamics ...

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  • Question 1
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    According to Hess’s Law, if a reaction takes place in several steps then its standard reaction enthalpy is

  • Question 2
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    Spontaneity in the context of chemical thermodynamics means

  • Question 3
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    For an adiabatic change

  • Question 4
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    According to the diagram given below, the value of H for conversion of A to B is

  • Question 5
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    Enthalpy of solution of a substance is the enthalpy change

  • Question 6
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    Directions: The following question has four choices out of which ONLY ONE is correct.

    Dissolution of ammonium chloride in water is an endothermic change. At constant temperature, it is accompanied by

  • Question 7
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    Directions: The following question has four choices out of which ONLY ONE is correct.

    What is the entropy change (in JK-1 mol-1) when one mole of ice is converted into water at 00C? (The enthalpy change for the conversion of ice to liquid water is 6.0 kJ mol-1 at 00C.)

  • Question 8
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    Enthalpy of atomization is enthalpy change on breaking

  • Question 9
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    If the enthalpy of oxidation of methanol to formaldehyde and water is -163 kJ, then what is the enthalpy of the formation of CH3OH? (Given: Enthalpy of formation of HCHO (l) is -116 kJ and enthalpy of formation of H2O (l) is -286 kJ.)

  • Question 10
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    Consider the reaction: 2C + O2  2CO2H = - 395.5 kJ/mol. Which of the following statements is/are correct for this reaction?

  • Question 11
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    The enthalpy and entropy changes for the reaction Br2(I) + CI2(g) 2 BrCI(g) are 30 kJ mol–1 and 105 JK–1 mol–1, respectively.

    The temperature at which the reaction will be in equilibrium is

  • Question 12
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    In a reversible process, Ssys + Ssurr is 

  • Question 13
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    Standard enthalpy and standard entropy changes for the oxidation of ammonia at 298 K are - 382.64 kJ mol-1 and - 145.6 J K-1 mol-1, respectively. Standard Gibbs energy change for the same reaction at 298 K is

  • Question 14
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    Directions: The following question has four choices out of which ONLY ONE is correct.

    The heat of neutralisation of acetic acid by sodium hydroxide is −50.6 kJ/mol, and the heat of neutralisation of a strong acid by a strong base is −55.9 kJ/mol. What is the value of H for the ionisation of CH3COOH?

  • Question 15
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    Which of the following reactions corresponds to the definition of enthalpy of formation?

  • Question 16
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    When a solid changes into liquid, the entropy

  • Question 17
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    For the reaction 2H2 + O2 2H2O, H = -571 kJ, bond energy of H - H = 435 kJ/mol and that of O - O = 498 kJ/mol. Calculate the average bond energy (in kJ/mol) of O - H bond using this data.

  • Question 18
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    The unit of entropy is

  • Question 19
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    Which one of the following relations is incorrect?

  • Question 20
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    Identify the correct statement for change of Gibbs energy for a system (Gsystem) at constant temperature and pressure.

  • Question 21
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    The lattice enthalpy of an ionic compound is the enthalpy change which occurs when 

  • Question 22
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    A thermodynamic state function is a physical quantity whose value 

  • Question 23
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    The amount of heat liberated when 1 mole of a substance is completely burnt in the presence of oxygen is known as

  • Question 24
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    Entropy is a state function and measures

  • Question 25
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    Bond energy of hydrogen gas is - 433 kJ. What is the bond dissociation energy of 0.5 mole of hydrogen gas?

  • Question 26
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    Hess's Law deals with

  • Question 27
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    If change in Gibbs energy ΔG is negative (< 0) at constant pressure and temperature

  • Question 28
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    If C6H6(I) + 15/2 O2(g)  3H2O(I) + 6CO2(g); = – 3264.6 kJ mol–1, then the energy obtained by burning 3.9 g of benzene in air is 

  • Question 29
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    For the process, dry ice (g), which of the following is true?

  • Question 30
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    By convention, standard enthalpy for formation of an element in reference state is:

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