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Redox Reactions Test - 4

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Redox Reactions Test - 4
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  • Question 1
    1 / -0
    The standard redox potentials (Eo) of the following reactions are as follows.

    I. MnO4- + 8H+ + 5e- Mn2+ + 4H2O Eo = 1.51 V
    II. Sn2+ Sn4+ + 2e- Eo = -0.15 V
    III. Cr2O72- + 14H+ + 6e- 2Cr3+ + 7H2O Eo = 1.33 V
    IV. Ce3+ Ce4+ + e- Eo = -1.61 V

    In which of the following options is the oxidising power of the various ions wrongly related?
  • Question 2
    1 / -0
    Directions: The following question has four choices out of which ONLY ONE is correct.

    In acidic medium, dichromate ion oxidizes ferrous ion to ferric ion. If the gram molecular weight of potassium dichromate is 294 g, its gram equivalent weight is
  • Question 3
    1 / -0
    Directions: The following question has four choices out of which ONLY ONE is correct.

    If equal volumes of 1 M KMnO4 and 1 M K2Cr2O7 solutions are allowed to oxidize Fe (II) to Fe (III) in acidic medium, then Fe (II) oxidization will be
  • Question 4
    1 / -0
    Directions: The following question has four choices out of which ONLY ONE is correct.

    Consider the following half reactions:

    Zn2+ Zn(s); E0 = - 0.76V
    Cu2+ Cu(s); E0 = - 0.34V

    Which of the following reactions is spontaneous?
  • Question 5
    1 / -0
    In the balanced equation H2SO4 + x HI H2S + y I2 + z H2O, what are the values of x, y and z?
  • Question 6
    1 / -0

    Redox reaction between copper and aqueous solution of silver nitrate happens when copper rod is dipped in silver nitrate solution. What happens in the final stage?

    Solution

    This is due to the formation of Cu2+  ions in the solution illustrated in following ionic reaction:

    Cu(S)+2Ag+(aq)--------------˃Cu2+(aq)+2Ag(s)

    Here, Cu is oxidized to Cu2+ (means relasing of 2 electrons from Cu to Cu2+ ) and Ag+ is reduced to Ag(s) (means gaining of 2 electrons from 2Ag+ to 2Ag ) and thus, silver converted into solid state and deposited on copper rod.

  • Question 7
    1 / -0
    The mass of H2O2 that is completely oxidised with 31.2 g of KMnO4 (molar mass = 158 g mol–1) in acidic medium is
  • Question 8
    1 / -0

    The formation of sodium chloride involves two half reaction, which clearly show involvement of electrons.
    2 Na (s) → 2 Na + (g) + 2e Cl2 (g) + 2e → 2 Cl (g)
    Sum of the half reactions gives
    2 Na(s) +Cl2 (g) → 2 Na+ Cl (s) or 2 NaCl (s)

    In terms of electron-transfer change, name the oxidising agent(s) and reducing agent(s)

    Solution

    According to the modern concept, loss of electrons is oxidation whereas gain of electrons is reduction.Redox reaction involves two half reactions, one involving loss of electron or electrons (oxidation) and the other involving gain of electrons or electrons (reduction)

    • Oxidizing agent is a species which can gain one or more electrons.
    • Reducing agent is a species which can lose one or more electrons.

    In the given reaction Sodium(Na) is loosing 2 electrons, thus it is the reducing agent. Chlorine(Cl) is gaining 2 electrons , thus it is oxidising agent.

  • Question 9
    1 / -0
    HBr and HI can reduce sulphuric acid. HCl can reduce KMnO4 and HF can reduce
  • Question 10
    1 / -0
    What is the reduction product in the reaction 2KMnO4 + 16HCl 5Cl2 + 2MnCl2 + 2KCl + 8H2O?
  • Question 11
    1 / -0
    The reaction  is
  • Question 12
    1 / -0
    Directions: The following question has four choices out of which ONLY ONE is correct.

    The oxidation number of carbon in CH2O is
  • Question 13
    1 / -0
    For the reaction between KMnO4 and H2O2, the number of electrons transferred per mole of H2O2 is:
  • Question 14
    1 / -0

    Oxidation and reduction always occur simultaneously, hence, the word “redox” was coined for this class of chemical reactions. In the following redox reaction, identify the species undergoing oxidation and reduction:

    3Fe3O4(s) + 8 Al (s) → 9 Fe (s) + 4Al2O3(s)

    Solution

    In the above reaction oxygen is transferred from Fe3O4 to Al, so Fe3O4 is reduced while Al is oxidised.

    As per definition of oxidation and reduction , loss of oxygen i.e  reduction occurs in Fe3O4   and  gain of oxygen i.e Oxidation occurs in  Al.

  • Question 15
    1 / -0

    The oxidation state of an element in a particular compound can be defined as:

    Solution

    The oxidation state of an element in a particular compound can be defined as the charge acquired by its atom on the basis of electronegative consideration from other atoms in the molecule.

    In other words, it represents the number of electrons gained or lost by the element or ion in the reaction that formed the compound. It is expressed as a positive or negative number that represents the ionic charge. For example, in sodium chloride, the oxidation states of sodium and chlorine are +1 and -1 respectively.

    Hence, the correct option is (A).

  • Question 16
    1 / -0
    The reduction potentials of A, B, C and D are 0.8 V, 0.79 V, 0.34 V and -2.37 V, respectively. Which element displaces all the other three elements?
  • Question 17
    1 / -0
    Oxygen has a positive oxidation state in
  • Question 18
    1 / -0
    In which of the following compounds does the carbon atom have zero oxidation state?
  • Question 19
    1 / -0
    Directions: The following question has four choices out of which ONLY ONE is correct.

    One mole of acidified K2Cr2O7 on reaction with excess KI will liberate ___ mole(s) of I2.
  • Question 20
    1 / -0

    The electron releasing tendency of the metals, zinc, copper and silver is in the order:

    Solution

    Zinc relases electrons to copper and copper releases electron to silver therefore the electron releasing tendency of the metals, zinc, copper and silver is in the order Zn>Cu>Ag.This is on the basis of electrochemical series or metal activity series.

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