A molecular ion is a covalently bonded set of two or more atoms, or of a metal complex, that can be considered to behave as a single unit and that has a net charge that is not zero. Unlike a molecule, which has a net charge of zero, this chemical species is an ion. . (The prefix poly- carries the meaning "many" in Greek, but even ions of two atoms are commonly described as polyatomic.)
In older literature, a polyatomic ion may instead be referred to as a radical (or less commonly, as a radical group). (In contemporary usage, the term radical refers to various free radicals, which are species that have an unpaired electron and need not be charged.)
A simple example of a polyatomic ion is the hydroxide ion, which consists of one oxygen atom and one hydrogen atom, jointly carrying a net charge of \(-1 ;\) its chemical formula is \(\mathrm{OH}^{-}\) In contrast, an ammonium ion consists of one nitrogen atom and "four" hydrogen atoms, with a charge of \(+1 ;\) its chemical formula is \(\mathrm{NH4^{+}}\)
Polyatomic ions often are useful in the context of acid-base chemistry, and in the formation of salts.