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Chemical Kineti...

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  • Question 1
    4 / -1

    The following data are for the decomposition of ammonium nitrite in aqueous solution

  • Question 2
    4 / -1

    The following kinetic data are provided for a reaction between A and B:

  • Question 3
    4 / -1

    SO2Cl2 → SO2 + Cl2 is a first order gas reaction with k = 2.2 × 10–5 sec–1 at 320oC. The percentage of SO2Cl2 decomposed on heating for 90 minutes is

  • Question 4
    4 / -1

    A substance ‘A’ decomposes in solution following the first order kinetics. Flask I contains 1 L of 1 M solution of A and flask II contains 100 ml of 0.6 M solution. After 8 hr, the concentration of A in flask I becomes 0.25 M. What will be time for concentration of A in flask II to become 0.3 M?

  • Question 5
    4 / -1

    If a is the initial concentration and k is the rate constant of a zero order reaction, the time for the reaction to go to completion will be

  • Question 6
    4 / -1

    The activation energy of a reaction is 58.3 kJ mol-1. The ratio of the rate constants at 305 K and 300 K is about (R = 8.3 JK-1 mol-1)

  • Question 7
    4 / -1

    The hydrolysis of ethyl acetate was carried out separately with 0.05 M HCl and 0.05 M H2SO4. The rate constants were found to be k1 and k2 respectively. Then

  • Question 8
    4 / -1

    A certain reaction A + B → P is of first order with respect to each reactant. If [A]0 =0.1 M, [B]0 = 5.0 M and the second order rate constant k is 6 × 10–3 M–1s–1the half-life of the reaction in seconds is

  • Question 9
    4 / -1

    Consider the following statements: The rate law for the acid catalysed hydrolysis of an ester being given as Rate = k [H+] [ester] = k’ [ester]. If the acid concentration is doubled at constant ester concentration
    1. the second order rate constant, k is doubled
    2. the pseudo first order rate constant, k is doubled
    3. the rate of the reaction is doubled.
    Which of the above statements are correct?

  • Question 10
    4 / -1

    2A + B → 3C for the reaction instant rate of reaction is...

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