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Hydrocarbons Test - 4

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Hydrocarbons Test - 4
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  • Question 1
    1 / -0

    Addition of HBr to HC ≡ C − CH2 − CH = CH2 gives

     

    HC ≡ C − CH2 − CHBr − CH3 and not H2C = CBr − CH2 − CH = CH2

    A triple bond is less reactive than a double bond.

    Solution

    Assertion is true, explanation is true and it is correct explanation of the assertion.

     

  • Question 2
    1 / -0

    Corey-House reaction can be used to prepare both symmetrical and unsymmetrical alkanes.

    It involves the interaction between lithium dialkyl-copper with an alkyl halide both of which may contain even or odd number of carbon atoms.

    Solution

    Assertion is true, explanation is true and it is correct explanation of the assertion.

     

  • Question 3
    1 / -0

    Melting point of neopentane is greater than that of n-pentane while the boiling point of neopentane is lower than n-pentane.

    Melting point depends upon packing in crystal lattice while boiling point depends upon surface area of the molecule.

    Solution

    Assertion is true, explanation is true and it is correct explanation of the assertion.

  • Question 4
    1 / -0

    2-Pentyne on hydrogenation in presence of Lindlar catalyst gives cis-1-pentene.

    Addition of hydrogen in a stereospecific reaction.

    Solution

    Assertion is true, explanation is true but it is nor correct explanation of the assertion.

  • Question 5
    1 / -0

    Which of the following involves the formation of an allylic carbocation?

    Solution

    All of the four involve allylic carbocation.

     

  • Question 6
    1 / -0

    Which of the following alkene will give same product when treated with HBr in presence and absence of benzoyl peroxide?

    Solution

    Symmetrical alkenes give same product whether the addition of HBr takes place in absence or presence of a peroxide. Among the four options, only 2-butene is symmetrical.

     

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