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Ionic Equlibrium Test - 7

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Ionic Equlibrium Test - 7
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  • Question 1
    4 / -1

    The conjugate acid of NH2- is

    Solution

    Conjugate acid of a base is formed by adding H+ to it
    NH2- + H+ → NH3
     

  • Question 2
    4 / -1

    Out of the following, amphiprotic species are

    I : HPO32-

    II OH-

    III H2PO4-

    IV HCO3-

    Solution

    Amphiprotic : can accept and Release H+
    Only H2PO4 & HCO3

  • Question 3
    4 / -1

    pH of an aqueous solution of NaCl at 85°C should be

    Solution

    NaCl Solution : pH is the, pH   of water.

    pH at 25°C <7

  • Question 4
    4 / -1

    1 c.c. of 0.1N HCl is added to 99 CC solution of NaCl. The pH of the resulting solution will be

    Solution

    Volume of resulting solution = 100 ml

  • Question 5
    4 / -1

    10 ml of  is mixed with 40 ml of . The pH of the resulting solution is

    Solution


    [H+] = 10–2
    pH = 2.

  • Question 6
    4 / -1

    If pKb for fluoride ion at 25°C is 10.83, the ionisation constant of hydrofluoric acid in water at this temperature is :

    Solution

    H+  H+ + F
    pKw = pKa + pKb
    [For conjugate Acid-Base]
    ⇒ pKa = 14 – 10.87 = 3.17
    Ka = 6.76 × 10–4

  • Question 7
    4 / -1

    The pH of an aqueous solution of 1.0 M solution of a weak monoprotic acid which is 1% ionised is:

    Solution

    Concentration of solution =C=1M
    Dissociation is α=0.01
    After dissociation, the concentration of H+ ions will be Cα=1×0.01=10−2
    pH=−log[H+]=−log(10−2) = +2

  • Question 8
    4 / -1

    If K1 & K2 be first and second ionisation constant of H3PO4 and K1 >> K2 which is incorrect.

    Solution




  • Question 9
    4 / -1

    The degree of hydrolysis of a salt of weak acid and weak base in it's 0.1 M solution is found to be 50%. If the molarity of the solution is 0.2 M, the percentage hydrolysis of the salt should be

    Solution

    % Hydrolysis does notdepend on the conc. in case of “Weak acid + weak base : Salt”

  • Question 10
    4 / -1

    What is the percentage hydrolysis of NaCN in N/80 solution when the dissociation constant for HCN is 1.3 × 10-9 and Kw = 1.0 × 10-14

    Solution

    Weak acid + Strong base : Salt


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