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Thermodynamics ...

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  • Question 1
    4 / -1

    ∆H = 30 kJ mol–1, ∆S = 75 J / k / mol. Find boiling temperature at 1 atm.

  • Question 2
    4 / -1

    Spontaneous adsorption of a gas on a solid surface is exothermic process because

  • Question 3
    4 / -1

    There is 1 mol liquid (molar volume 100 ml) in an adiabatic container initial, pressure being 1 bar Now the pressure is steeply increased to 100 bar, and the volume decreased by 1 ml under constant pressure of 100 bar. Calculate ∆H and ∆E. [Given 1 bar = 105 N/m2]

  • Question 4
    4 / -1

    The ratio of P to V at any instant is constant and is equal to 1, for a monoatomic ideal gas under going a process. What is the molar heat capacity of the gas

  • Question 5
    4 / -1

    The entropy values (in J K–1 mol–1) of H2 (g) = 130.6 Cl2(g) = 223 and HCl(g) = 186.7 at 298 K and 1 atm pressure are given. Then entropy change for the reaction.

  • Question 6
    4 / -1

    A mixture of 2 mole of CO(g) and one mole of O2 in a closed vessel, is ignited to convert the carbon monoxide to carbon dioxide. If ∆H and ∆U are enthalpy and internal energy change. Then

  • Question 7
    4 / -1

    For the reaction of one mole zinc dust with one sulphuric acid in a bomb calorimeter, ∆U and w correspond to :

  • Question 8
    4 / -1

    If the enthalpies of formation of Al2O3 and Cr2O3 are – 1596 kJ and – 1134 kJ respectively, then the value of ∆H for the reaction ; 2Al + Cr2O3 → 2Cr + Al2O3 is :

  • Question 9
    4 / -1

    The internal energy change when a system goes from state A to B is 40 kJ/mole. If the system goes from A to B by a reversible path and returns to state A by an irreversible path what would be the net change in internal energy

  • Question 10
    4 / -1

    ∆G° for the reaction x + y → z is – 4.606 kcal. The value of equilibrium constant of the reaction at 227°C is : (R = 2.0 cal K–1 mol–1 )

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