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Chemistry Test 159

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Chemistry Test 159
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Weekly Quiz Competition
  • Question 1
    4 / -1

    Which statement is incorrect about X ?

    Solution

     

  • Question 2
    4 / -1

    Solution

     

  • Question 3
    4 / -1

    Solution

    CH≡C–CH2CH2C≡C–CH3 +CH3Li

     

  • Question 4
    4 / -1

    Which of the following alkyl bromides undergo fastest SN1 reaction in water ?

    Solution

    The most stable intermediate carbocation is formed from both . However (B) is less stable, and hence more reactive.

     

  • Question 5
    4 / -1

    Directions For Questions

    NH3(g) is sealed in a U-tube manometer of uniform area of cross-section at 80 cm of Hg, as shown

    ...view full instructions

    After sometime, due to the dissociation of NH3, it was observed that the air column has shrunk by 5cm. Assuming that temperature remains constant, what is the degree of dissociation of NH3 ?

    Solution

    For air : P1V1 = P2V2

    ⇒ 80 × 25 = P2 × 20 

    ⇒ P2 = 100cm for Hg

    For the left column :-

    Pleft = Pright + 10cm of Hg

    ⇒ Pleft = 110 cm of Hg

     

  • Question 6
    4 / -1

    To the dissociation reaction was added, maintaining its partial pressure constant.

    Solution

    Since O2 is added at constant partial pressure, the total pressure decreases and the total volume increases.

    2N2O5(g) ⇌ 4NO2(g) + O2(g)

    Let partial pressure      x   y   z

    at initial eql be

    Pressure after

    adding O2,    x/a    y/a    z

    assuming that 

    volume increases

    to 'a' times the initial

    volume

     

  • Question 7
    4 / -1

    1 mole of an ideal monoatomic gas occupying a volume of 20L at 1 atm undergoes single step adiabatic compression against a constant external pressure of 10 atm. The final volume of gas is - 

    Solution

     

  • Question 8
    4 / -1

    What is the solubility of CaCO3 in 0.4M H2CO3 solution ? Assume H2CO3 to be stable in aqueous solution for the duration of the reaction and Ca(HCO3)2 to be completely soluble. Ksp of CaCO3 = 10–9M K1, K2 of H2CO3 = 10–7 and 10–11 respectively

    Solution

     

  • Question 9
    4 / -1

    (i) Reaction is a zero order reaction

    (ii) Rate constant for the reaction is 0.02 s–1

    (iii) If concentration of A is changed, then rate constant changes, but rate of reaction remains constant.

    (iv) The reaction is a complex reaction

    Solution

    (i)  (from the graph), it is a zero order reaction.

    (ii) unit of rate constant for a zero order reaction is mol L–1s–1

    (iii) Rate constant does not depend on concentration of the reaction

    (iv) Zero order reaction is always a complex reaction.

     

  • Question 10
    4 / -1

    Electrons in H atom get excited from the ground state to an orbit in which the wavelength of the electron is 10 times the wavelength of an electron in the ground state of He+. How many spectral lines are observed in the visible range when these electrons are de-excited to the ground state ?

    Solution

     

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