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JEE Advanced Mix Test 12

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JEE Advanced Mix Test 12
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Weekly Quiz Competition
  • Question 1
    4 / -1

    Graph shows a hypothetical speed distribution for a sample of N gas particles (for V > V0 ; 

    Solution

  • Question 2
    4 / -1

    Pick the correct statement(s) :

    Solution

    Since PV = nRT therefore P and V both can change simultaneously keeping temperature constant. 

  • Question 3
    4 / -1

    STATEMENT–1: A gas is kept in an insulated cylinder with a movable piston, in compressed state. As the piston is released, temperature of the gas decreases.

    STATEMENT–2: According to the kinetic theory of gas, a molecule colliding with the piston must rebound with less speed than it had before the collision. Hence average speed of the molecules is reduced.

    Solution

    Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1

  • Question 4
    4 / -1

    Statement-1: As the temperature of the blackbody increases, the wavelength at which the spectral intensity (Eλ) is maximum decreases.

    Statement-2: The wavelength at which the spectral intensity will be maximum for a black body is proportional to the fourth power of its absolute temperature.

    Solution

    From Wein's law λmT = constant i.e., peak emission wavelength 

    Hence as T increase λm decreases.

  • Question 5
    4 / -1

    Directions For Questions

    The atmospheric lapse rate For small volumes of gas, according to kinetic theory of gases, all parts of the gas are at the same temperature. But for huge volumes of gas like atmosphere, assumption of a uniform temperature throughout the gas is not valid. Different parts of the atmosphere are at different temperatures. Apart from the surface of the earth, variations also occur in temperature at different heights in the atmosphere.

    The decrease in temperature with height called the atmospheric lapse rate is similar at various locations across the surface of the Earth. By analyzing the data collected at various locations, it is found that average global lapse rate is – 6.7 °C/Km.

    The linear decrease with temperature only occurs in the lower part of the atmosphere called the troposphere. This is the part of the atmosphere in which weather occurs and our planes fly. Above the troposphere is the stratosphere, with an imaginary boundary separating the two layers. In the stratosphere, temperature tends to be relatively constant.

    Absorption of sunlight at the Earth’s surface warms the troposphere from below, so vertical convection currents are continually mixing in the air. As a parcel of air rises, its pressure drops and it expands. The parcel does work on its surrounding, so that its internal energy and therefore, its temperature drops. Assume that the vertical mixing is so rapid as to be adiabatic and the quantity TP(1 – λ)/λ has a uniform value through the layers of troposphere. (M is molecular mass of the air, R is universal gas constant, g is gravitational acc., P and T are pressure and temperature respectively at the point under consideration and y is height.)

    ...view full instructions

    If behaviour of the mixing of parcels of air is approximately assumed to be adiabatic then lapse rate can be expressed as :

    Solution

  • Question 6
    4 / -1

    Directions For Questions

    The atmospheric lapse rate For small volumes of gas, according to kinetic theory of gases, all parts of the gas are at the same temperature. But for huge volumes of gas like atmosphere, assumption of a uniform temperature throughout the gas is not valid. Different parts of the atmosphere are at different temperatures. Apart from the surface of the earth, variations also occur in temperature at different heights in the atmosphere.

    The decrease in temperature with height called the atmospheric lapse rate is similar at various locations across the surface of the Earth. By analyzing the data collected at various locations, it is found that average global lapse rate is – 6.7 °C/Km.

    The linear decrease with temperature only occurs in the lower part of the atmosphere called the troposphere. This is the part of the atmosphere in which weather occurs and our planes fly. Above the troposphere is the stratosphere, with an imaginary boundary separating the two layers. In the stratosphere, temperature tends to be relatively constant.

    Absorption of sunlight at the Earth’s surface warms the troposphere from below, so vertical convection currents are continually mixing in the air. As a parcel of air rises, its pressure drops and it expands. The parcel does work on its surrounding, so that its internal energy and therefore, its temperature drops. Assume that the vertical mixing is so rapid as to be adiabatic and the quantity TP(1 – λ)/λ has a uniform value through the layers of troposphere. (M is molecular mass of the air, R is universal gas constant, g is gravitational acc., P and T are pressure and temperature respectively at the point under consideration and y is height.)

    ...view full instructions

    Mechanical equilibrium of the atmosphere requires that the pressure decreases with altitude according to  Assuming free fall acceleration to be uniform, then lapse rate is given by

    Solution

  • Question 7
    4 / -1

    Directions For Questions

    The atmospheric lapse rate For small volumes of gas, according to kinetic theory of gases, all parts of the gas are at the same temperature. But for huge volumes of gas like atmosphere, assumption of a uniform temperature throughout the gas is not valid. Different parts of the atmosphere are at different temperatures. Apart from the surface of the earth, variations also occur in temperature at different heights in the atmosphere.

    The decrease in temperature with height called the atmospheric lapse rate is similar at various locations across the surface of the Earth. By analyzing the data collected at various locations, it is found that average global lapse rate is – 6.7 °C/Km.

    The linear decrease with temperature only occurs in the lower part of the atmosphere called the troposphere. This is the part of the atmosphere in which weather occurs and our planes fly. Above the troposphere is the stratosphere, with an imaginary boundary separating the two layers. In the stratosphere, temperature tends to be relatively constant.

    Absorption of sunlight at the Earth’s surface warms the troposphere from below, so vertical convection currents are continually mixing in the air. As a parcel of air rises, its pressure drops and it expands. The parcel does work on its surrounding, so that its internal energy and therefore, its temperature drops. Assume that the vertical mixing is so rapid as to be adiabatic and the quantity TP(1 – λ)/λ has a uniform value through the layers of troposphere. (M is molecular mass of the air, R is universal gas constant, g is gravitational acc., P and T are pressure and temperature respectively at the point under consideration and y is height.)

    ...view full instructions

    The value of theoretical lapse rate on the earth is (use g = 9.8 m/s2 ; R = 8.3 J/mol-k and M = 29 g/mol)

    Solution

  • Question 8
    4 / -1

    The figures given below show different processes (relating pressure P and volume V) for a given amount of an ideal gas. ΔW is work done by the gas and ΔQ is heat absorbed by the gas.

    Solution

  • Question 9
    4 / -1

    The hybridisation and geometry of the anion of ICl3 in liquid phase is :

    Solution

  • Question 10
    4 / -1

    Select the incorrect statement about the XeF6.

    Solution

    In tetramer, four square pyramidal XeF5+ ions are joined to two similar ions by means of two bridging F- ions.

    The Xe-F distances are 1.84 Å on the square pyramidal units and 2.23 Å and 2.60 Å in the bridging groups. The solid has various crystalline forms, of which three are tetrameric and a fourth has both hexamers and tetramers.

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