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Solid State Test - 9

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Solid State Test - 9
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  • Question 1
    1 / -0

    Amorphous form of silica is

    Solution

    Fumed silica, also known as pyrogenic silica because it is produced in a flame, consists of microscopic droplets of amorphous silica fused into branched, chainlike, three-dimensional secondary particles which then agglomerate into tertiary particles.

    Tridymite is a high-temperature polymorph of silica and usually occurs as minute tabular white or colorless pseudo-hexagonal crystals.
    The mineral cristobalite is a high-temperature polymorph of silica that has the same chemical formula as quartz, SiO2, but a distinct crystal structure.
    Asbestos is a set of six naturally occurring silicate minerals, which exist in the form of long, thin fibrous crystals.

     

  • Question 2
    1 / -0

    In a face centered cubic lattice, a unit cell is shared equally by how many unit cells?

    Solution

    Each unit cell shared by 6 unit cells.

     

  • Question 3
    1 / -0

    The particles, when placed in adjacent rows, show a horizontal as well as vertical alignment and form squares. This type of packing is known as

    Solution

    When building the three dimensional lattice, the centres of the spheres are aligned vertically as well as horizontally. This packing is then known as square close packing.

     

  • Question 4
    1 / -0

    Find the respective coordination numbers of cations and anions in calcium fluoride structure.

    Solution

    Simple ionic structures are described by two coordination numbers, one for each type of ion. Calcium fluoride (CaF2) is an (8, 4) structure, meaning that each cation Ca2+ is surrounded by eight F- anion neighbours, and each anion F- by four Ca2+.

     

  • Question 5
    1 / -0

    The coordination number of barium ions (Ba2+) in barium fluoride (BaF2) is 8. What must be the coordination number of fluoride ions?

    Solution

    The coordination number of barium ions tells us that it is surrounded by eight fluoride ions (charge 8 × (–1) = –8). In order to balance out the eight negative charges, we need four barium ions (charge 4 × (+2) = +8). Hence, the coordination number of the fluoride ions must be 4.

     

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