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Electrochemistry Test - 4

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Electrochemistry Test - 4
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  • Question 1
    1 / -0

    Zinc/Silver oxide cell is used in electric watches.

    Zn → Zn2+ + 2eE0 = - 0.76 V

    Ag2O + H2O + 2e- → 2Ag + 2OHE0 cell = 0.8 V

    ΔG0 for the reaction is

    Solution

    Eo = 0.8 - (- 0.76) = 1.56 V
    ΔGo = - nFEo = - 2 × 96,500 × 1.56
    ΔGo = - 3,01,080 CV = - 3.01 ×105 J (1 CV = 1 J)

     

  • Question 2
    1 / -0

    The unit of conductance is

    Solution

    Conductance is the degree to which an object conducts electricity. It is calculated as the ratio of the current which flows to the potential difference present. This is the reciprocal of the resistance, and is measured in siemens or mhos (Ω-1).

     

  • Question 3
    1 / -0

    Which of the following statements is correct?

    Solution

    The equivalent conductance of both strong and weak electrolytes increases with dilution. This is because with the increase in dilution (decrease in concentration), ions become farther apart, and inter-ionic forces (i.e. forces of attraction between unlike ions and forces of repulsion between like ions) decrease considerably, so that greater number of ions are able to migrate to the electrodes. In addition, due to change in equilibrium, the electrolyte undergo further ionisation from the same mass in solution (in order to balance the effect).

    Hence, more ions (conducting species) are introduced into the solution.

     

  • Question 4
    1 / -0

    Choose the correct statement from among the following.

    Solution

    Specific conductance of H2SO4 decreases with dilution as the number of ions available for carrying current per unit volume decreases with dilution. Hence, option (2) is correct.

    All the other statements are wrong.
    Conductance of metallic conductors decreases with the rise in temperature. Hence, optrion (1) is incorrect.

    Cane sugar is a non-conductor. Hence, optrion (3) is incorrect.
    Conductance of electrolytic conductors increases with rise in temperature. Hence, optrion (4) is incorrect.

     

  • Question 5
    1 / -0

    Molar conductivity has the unit of

    Solution

    Molar conductivity is defined as the conductivity of an electrolyte solution divided by the molar concentration of the electrolyte and so, it measures the efficiency with which a given electrolyte conducts electricity in a solution. Its units are siemens per centimeter per molarity, or siemens centimeter - square per mole (Ω-1 cm2 mol-1).

     

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