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Thermodynamics ...

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  • Question 1
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    What is the absolute enthalpy of neutralisation of the following reaction?

    MgO (s) + 2HCl (aq) → MgCl2 (aq) + H2O (l)

  • Question 2
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    The enthalpy change involved in the oxidation of glucose is -2880 kJ/mol and 25% of this energy is available for muscular work. If 100 kJ of muscular work is needed to walk 1 km, then what is the maximum distance that a person will be able to walk after consuming 120 g of glucose?

  • Question 3
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    The species, which by definition has zero standard molar enthalpy of formation at 298 K, is

  • Question 4
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    Which of the following pairs of chemical reactions is certain to result in a spontaneous reaction?

  • Question 5
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    Consider the following reactions:

    (i) H2O (l) → H2O (g), T = 25°C vessel open to atmosphere with 50% relative humidity.
    (ii) H2O (s) → H2O (l), T = 25°C, P = 1 atm

    Which of these will be spontaneous under the given conditions of temperature and pressure?

  • Question 6
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    The factor of ∆G values is important in metallurgy. The ∆G values for the following reactions at 800oC are given as:

    S2 (s) + 2O2 (g) → 2SO2 (g); ∆G = - 544 kJ
    2Zn (s) + S2 (s) → 2ZnS (s); ∆G = - 293 kJ
    2Zn (s) + O2 (g) → 2ZnO (s); ∆G = - 480 kJ

    What is ∆G for the following reaction?

    2ZnS (s) + 3O2 (g) → 2ZnO (s) + 2SO2 (g)

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