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Thermodynamics ...

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  • Question 1
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    On the basis of thermochemical equations (a), (b) and (c), what is the enthalpy of formation of ethane? (Assume that enthalphy of formation of ethane is p.)

    (a) C (s) + O2 → CO2 (g); ∆H = x kJ
    (b) H2 (g) + ½ O2 (g) → H2O (l); ∆H = y kJ
    (c) C2H6 (g) + 7/2 O2 (g) → 2CO+ 3H2O (g); ∆H = z kJ

  • Question 2
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    The standard molar entropy of H2O (l) is 70 JK-1. The standard molar entropy of H2O (s) is

  • Question 3
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    Consider the reaction:

    A + B ⇌ C + D

    At 27oC, for which K = 102, what will be the values of ∆G and ∆Go?

  • Question 4
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    The essential condition for feasibility of a reaction is that the

  • Question 5
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    After dividing a substance into two equal parts, which of the following properties of the substance reduces to half?

  • Question 6
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    Match the terms in Column - I of the following table with the expressions in Column - II:

    Column - I Column - II
    A. Enthalpy 1. U + pV
    B. Work done during an adiabatic change 2. H − TS
    C. Gibbs energy 3. nCv∆T

  • Question 7
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    W is the amount of work done to melt an ice cube. Heat transfer which took place in the reaction is q. What is the change in the internal energy (∆U) of the system?

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