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Chemical Kineti...

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  • Question 1
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    Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.

    Assertion (A): Rate of reaction doubles when concentration of reactant is doubled if it is a first order reaction.

    Reason (R): Rate constant also doubles.

  • Question 2
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    Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.

    Assertion (A): Dust particles suspended in the air inside unheated gain electrons can sometimes react explosively.

    Reason (R): The dust particles have a large surface area for the reaction.

  • Question 3
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    Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.

    Assertion (A): The rate of reaction increases with increase in temperature.

    Reason (R): The reactant molecules collide less frequently.

  • Question 4
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    Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.

    Assertion (A): Elementary reactions have the same value of order and molecularity.

    Reason (R): Molecularity is the number of molecules that participate in the reaction, while order is an experimental quantity.

  • Question 5
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    Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.

    Assertion (A): For complex reactions molecularity and order are not the same.

    Reason (R): Order of reaction may be zero.

  • Question 6
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    Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.

    Assertion (A): Hydrolysis of an ester follows first order kinetics.

    Reason (R): Concentration of water remains nearly constant during the course of the reaction.

  • Question 7
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    Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.

    Assertion (A): For a first order reaction, half-life period is independent of initial concentration of the reacting species.

    Reason (R): The half-life of a reaction is the time in which the reactant concentration is reduced to one half of its initial concentration.

  • Question 8
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    Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.

    Assertion (A): Order of the reaction can be zero or fractional.

    Reason (R): We cannot determine order from a balanced chemical equation.

  • Question 9
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    In the following questions a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices.

    Assertion: Order of the reaction can be zero or fractional.

    Reason : We cannot determine order from a balanced chemical equation.

  • Question 10
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    In the following questions a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices.

    Assertion : Order and molecularity are same.

    Reason : Order is determined experimentally and molecularity is the sum of the stoichiometric coefficient of rate determining elementary step.

  • Question 11
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    In the following questions a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices.

    Assertion : The enthalpy of reaction remains constant in the presence of a catalyst.

    Reason : A catalyst participating in the reaction, forms a different activated complex and lowers down the activation energy but the difference in energy of reactant and product remains the same.

  • Question 12
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    In the following questions a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices.

    Assertion : Rate constants determined from Arrhenius equation are fairly accurate for simple as well as complex molecules.

    Reason : Reactant molecules undergo chemical change irrespective of their orientation during collision.

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