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Chemical Kinetics Test - 13

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Chemical Kinetics Test - 13
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  • Question 1
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    Study of rate of chemical reaction is known as

    Solution

    Chemical Kinetics deals with rate of a Chemical reactions.

  • Question 2
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    Which among the following is an instantaneous reaction?

    Solution

    Precipitation of AgCl is an example of instantaneous reaction.

  • Question 3
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    The rate of reaction can be measured as  

    Solution

    Rate of reaction can be measured in terms of Rate of disappearance of reactant or rate of apperance of product.

  • Question 4
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    Rate of reaction for the combustion of propane is equal to 

    C3H8(g) + 5O2(g) → 3CO2(g) + 4H2O(g)

    Solution

  • Question 5
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    What is the order of a reaction which has a rate expression ; Rate = 

    Solution

    Total order of reaction = order wrt to A + order wrt to B.

  • Question 6
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    Molecularity of a reaction

    Solution

    Molecularity is defined as the number of molecules, atoms, or radicals that must collide simultaneously in order for the reaction to take place. It is always a whole number (except zero) and cannot be negative.

  • Question 7
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    For which of the following reaction the units of rate constant and rate of the reaction are same?

    Solution

  • Question 8
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    The rate of chemical reaction becomes double for every 10o rise in temperature because of

    Solution

    With increase in temperature molecular collisions increases therefore rate of reaction doubles.

  • Question 9
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    The rate is independent of the concentration of the reactants in

    Solution

  • Question 10
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    A reaction whose order is different from the actual due to large excess concentration of one of the reactants is called?

    Solution

    A reaction whose order is different from the actual due to large excess concentration of one of the reactants is called pseudo 1st order reactions.

  • Question 11
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    The role of catalyst in a chemical reaction is to change the

    Solution

    Role of catalyst is to decrease the activation energy of reaction.

  • Question 12
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    Rate of ionic reactions are generally

    Solution

    Ionic reactions occur very fast.

  • Question 13
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    The metabolism of hormones in human body is an example of

    Solution

    It is pseudo first order reaction.

  • Question 14
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    If a reaction proceeds with a uniform rate throughout, the reaction is

    Solution

    Rate of reaction is independent of concentration of reactant.

  • Question 15
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    Which among the following is an example of photochemistry used in our daily life?

    Solution

    Photography is an example of photochemistry used in our daily life.

  • Question 16
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    The ionic reactions are generally very fast because

    Solution

    Ionic compounds in solution react faster than molecular compounds. This is because Ionic compounds break apart to form free ions. Therefore, there are no bonds to break so the reaction is fast. Covalent compounds, on the other hand, have to break bonds first as they react, so the reaction is often slower.

  • Question 17
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    The rate constant of the reaction at temperature 200 K is 10 times less than the rate constant at 400 K. The activation energy of the reaction is  

    Solution

  • Question 18
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    Which among the following is an instantaneous reaction?

    Solution

    Precipitation of AgCl is an example of instantaneous reaction.

  • Question 19
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    The half life of a reaction is halved as the initial concentration of the reactant is doubled. The order of the reaction is

    Solution

    For second order reaction half life is inversely related to concentration of reactant.

  • Question 20
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    If 75% of a first order reaction was completed in 32 min, then 50% of the reaction was completed in

    Solution

    75% completion means 2 half lifes so 50% completion means only one half life.

  • Question 21
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    Milk turns sour at 40°C three times faster than it does at 0°C, this shows that activation energy of souring of milk (in cal) is

    Solution

  • Question 22
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    In a reaction, → Product, rate is doubled when the concentration of is doubled, and rate increases by a factor of 8 when the concentrations of both the reactants (Aand B) are doubled, rate law for the reaction can be written as 

    Solution

    The correct answer is option B
    When conc. of B is doubled, the rate is doubled. 
    So, Order w.r.t.  [B] is 1.
    The rate increases by a factor of 8 when conc. of [A] and [B] are doubled.
    So, Order w.r.t.  [A] is 2.
    Overall Rate is 
    Rate=k[A]2[B]

  • Question 23
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    Thermal decomposition of a compound is of first order. If 50% of a sample of a compound is decomposed in 120 min, the time taken for 90% completion is

    Solution

  • Question 24
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    In the catalyzed decomposition of benzene diazonium chloride, 

    Half life period is found to be independent of the initial concentration of the reactant. After 10 min, the volume of Ngas collected is 10 L and after the reaction is complete, it is 50 L. Hence, the rate constant of the reaction(in min-1) is

    Solution

  • Question 25
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    Decomposition of  H2Owas studied by titration against KMnOsolution. It was found that 0.4 mol of H2Owas reduced to 0.2 mol in 20 min and to 0.1 mol in 40 min and to 0.05 mol after 1 hr, the order of reaction must be

    Solution

    For 1st order reaction, 
    Co  (t1/2)→Co/2  (t1/2)→Co/4  (t1/2)→…….Co/2n
    Here, t1/2 = 20
    So after 1st half life, concentration should be 0.4/2 = 0.2 
    After 2nd half life, concentration should be 0.4/4 = 0.1
    This is correct with given data. So the order is 1st order. 

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