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Surface Chemistry Test - 21

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Surface Chemistry Test - 21
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  • Question 1
    1 / -0

    Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.

    Assertion (A): Extent of adsorption of adsorbate from solution phase increases with increase in amount of adsorbate in solution.

    Reason (R): Freundlich’s equation describes the behaviour of adsorption from a solution.

    Solution

    Freundlich’s equation describes the behaviour of adsorption from a solution.

    It also written as

    x = mass of adsorbate

    m = mass of adsorbent

    p = equilibrium pressure of the gaseous adsorbate in case of experiments made in gas phase (gas/ solid interaction with gaseous species/adsorbed species).

    C = equilibrium constant of adsorbate in case of experiments made with an aqueous solution in contact with dispersed solid phase (dissolved species/adsorbed species).

    k and n are constants of a given adsorbate and adsorbent at a given temperature (from there, the item isotherm needed to avoid significant gas pressure fluctuations due to uncontrolled temperature variations in the case of adsorption experiments of a gas onto a solid phase).

  • Question 2
    1 / -0

    Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.

    Assertion (A): Extent of physisorption of a gas increases with decrease in temperature.

    Reason (R): It is due to decrease in strength of van der Waals forces.

    Solution

    In physisorption, phenomenon particles are held to the surface by weak van der Waals’ force of attraction which get destroyed due to increase in temperature.

  • Question 3
    1 / -0

    Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.

    Assertion (A): At the equilibrium position in the process of adsorption ∆H = T∆S.

    Reason (R): Adsorption is accompanied by decrease in surface energy.

    Solution

    ∆G = ∆H – T∆S Gibbs Free energy equation Adsorption is a spontaneous process so ∆G is negative. At equilibrium it becomes zero and ∆H = T∆S is attained.

  • Question 4
    1 / -0

    Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.

    Assertion (A): Activated adsorption is also known as chemical adsorption or chemisorption.

    Reason (R): It involves formation of chemical bonds between adsorbent and reactants.

    Solution

    Activated adsorption is also known as chemical adsorption or chemisorption as it involves formation of chemical bonds between adsorbent and reactants.

  • Question 5
    1 / -0

    Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.

    Assertion (A): An ordinary filter paper impregnated with collodion solution stops the flow of colloidal particles.

    Reason (R): Pore size of the filter paper becomes more than the size of colloidal particle.

    Solution

    Pore size of the filter paper becomes less than the size of colloidal particles hence colloidal particles do not flow through it.

  • Question 6
    1 / -0

    Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.

    Assertion (A): Detergents with low CMC are more economical to use.

    Reason (R): Cleansing action of detergents involves the formation of micelles. These are formed when the concentration of detergents becomes equal to CMC.

    Solution

    Cleansing of clothes takes place by micelles and their formation starts at CMC. The lesser is the CMC, the better and more economical is the detergent.

  • Question 7
    1 / -0

    Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.

    Assertion (A): Colloidal solutions do not show Brownian motion.

    Reason (R): Brownian motion is responsible for stability of sols.

    Solution

    Colloidal particles show Brownian movement and it is responsible for the stability of colloidal solution.

  • Question 8
    1 / -0

    Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.

    Assertion (A): Coagulation power of Al3+ is more than Na+.

    Reason (R): Greater the valency of the flocculating ion added, greater is its power to cause precipitation (Hardy-Schulze rule).

    Solution

    According to Hardy-Schulze law, the greater is the valency of the coagulating ion, the more is the power to coagulate the colloidal solution. Thus, the coagulation power of Al3+ is greater than that of Na+.

  • Question 9
    1 / -0

    Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.

    Assertion (A): Colloidal solutions show colligative properties.

    Reason (R): Colloidal particles are large in size.

    Solution

    Colloidal particles are large in size and hence the number of particles is lesser than the true solution. The lesser number of particles results in lower colligative properties.

  • Question 10
    1 / -0

    Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.

    Assertion (A): Colloids are stable.

    Reason (R): Brownian movement has a stirring effect, which does not allow the particles to settle.

    Solution

    Colloids are stable due to Brownian movement which is the movement of colloidal particles striking against the dispersion medium. It prevents them from settling down.

  • Question 11
    1 / -0

    Directions: These questions consist of two statements, each printed as Assertion and Reason. While answering these questions, you are required to choose any one of the following four responses.

    Assertion: Detergents with low CMC are more economical to use.

    Reason: Cleansing action of detergents involves the formation of micelles. These are formed when the concentration of detergents becomes equal to CMC.

    Solution

    Detergents with low CMC are more economical to use as they involve the formation of micelle which is used for cleaning oil and dirt from our cloth. Micelle formation takes place when the concentration of detergent becomes equal to CMC.

  • Question 12
    1 / -0

    Directions: These questions consist of two statements, each printed as Assertion and Reason. While answering these questions, you are required to choose any one of the following four responses.

    Assertion : The value of colligative properties are of small order for colloids as compared to true solution.

    Reason : Number of particles in colloidal solution is comparatively smaller than true solutions.

    Solution

    Colligative properties depend upon the number of particles.

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