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Coordination Compounds Test - 4

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Coordination Compounds Test - 4
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Weekly Quiz Competition
  • Question 1
    1 / -0

    IUPAC name of [Ni(CO)4] is

    Solution

    IUPAC name of [Ni(CO)4] is tetracarbonylnickel(0).
    Oxidation state of Ni is x + 4(0) = 0; x = 0.

     

  • Question 2
    1 / -0

    The IUPAC name of the complex [Ni(NH3)4] [NiCl4] is

    Solution

    The IUPAC name of the complex [Ni(NH3)4] [NiCl4] is tetraamminenickel(II)-tetrachloronickelate(II).

     

  • Question 3
    1 / -0

    Directions For Questions

    In the following question, a statement of Assertion is given; followed by a corresponding statement of Reason just below it. Mark the correct answer as:

    (a) If both assertion and reason are true and reason is the correct explanation of assertion
    (b) If both assertion and reason are true, but reason is not the correct explanation of assertion
    (c) If assertion is true statement, but reason is false
    (d) If both assertion and reason are false

    ...view full instructions

    Assertion: [Ni(en)3Cl2]Cl2 (en = ethylene diamine) has lower stability than [Ni(NH3)6Cl2].
    Reason: In [Ni(en)3Cl2], the geometry of Ni is trigonal bipyramidal.

    Solution

    Stability is more in case of chelating ligands. In [Ni(en)3]Cl2, the geometry of nickel is octahedral.

     

  • Question 4
    1 / -0

    Which of the following complexes is/are of low spin?

    Solution

    The complex has a square planar shape.
    CN- is a strong-field ligand.
    The d electron configuration of Ni2+ is d8.
    The splitting energy is large.
    Therefore, the complex is of low spin.

     

  • Question 5
    1 / -0

    Vitamin B12 is a complex of

    Solution

    Vitamin B12 is a complex of cobalt(III) ion.

     

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