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General Principles of Isolation of Elements Test - 2

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General Principles of Isolation of Elements Test - 2
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  • Question 1
    1 / -0

    Sulphide ores are converted into oxides for the extraction of metals because

    Solution

    The formation of metal oxides is an exothermic process, which makes it spontaneous at ordinary temperatures, but it proceeds with a decrease in entropy, because of which the Gibb's energy for the process becomes less negative with the increase in temperature and the process becomes less favourable.

    Hence, at higher temperatures, it becomes easier to extract a metal from its oxides.
    However, in case of sulphides, there is no such advantage. Hence, sulphides are converted into oxides.

     

  • Question 2
    1 / -0

    Fluorspar in the electrolytic reduction of alumina is dissolved in fused cryolite (Na3AlF6)

    Solution

    CaFis added to maintain the fluidity of the mass, so that the molten aluminium metal sinks to the bottom of the electrolytic cell, from where it is collected through the tap hole.

     

  • Question 3
    1 / -0

    Blister copper is

    Solution

    Blister copper is the copper produced by smelting and is 96 to 99 percent pure (partially pure copper). The trapped bubbles of SO2 give it a blistery surface, which is why it is called blister copper.

     

  • Question 4
    1 / -0

    Sphalerite and calamine are ores of

    Solution

    Calamine is ZnCO3 and sphalerite is a sulphide of zinc with iron replacing zinc at some of the lattice points. The latter is the chief ore of zinc.

     

  • Question 5
    1 / -0

    During the extraction of Al, coke powder is spread over the molten electrolyte in order to

    Solution

    The layer of coke spread on the electrolyte, serves as an insulator. It also to some extent compensates for the carbon lost from anode through oxidation by the oxygen discharged at the anode, as a product of electrolysis.

     

  • Question 6
    1 / -0

    Which of the following methods is used for refining silver metal, containing lead impurity?

    Solution

    Cupellation is heating the impure metal in cupel which is a pan made of bone ash in a blast of air. The lead impurity escapes as its volatile oxide.

     

  • Question 7
    1 / -0

    There are some chemical methods involved during the refining of metals. These methods are:

    (I) Liquation
    (II) Distillation
    (III) Cupellation
    (IV) Zone refining

    Which method(s) is/are used to extract silver from argentiferous lead?

    Solution

    Ag from argentiferous lead is separated out by distillation method as it is volatile in nature. Ag is purified by cupellation process.

     

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