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Some Basic Concepts of Chemistry Test - 22

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Some Basic Concepts of Chemistry Test - 22
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  • Question 1
    1 / -0
    Assertion : 20 gm of argon (atomic mass of Ar $$=40)$$ occupies volume of $$22400\ cm^3$$ at STP.
    Reason : 20 gm of Neon (atomic mass of $$Ne=20$$) occupies a volume of $$22400\ cm^3$$ at STP.
    Solution
    20 g of argon is 0.5 moles and it occupies $$(0.5\times 22400=)11200\ cm^3$$ at STP.
    20 g of Neon is 1 mole and occupies a volume of $$22400\ cm^3$$ at STP.
  • Question 2
    1 / -0
    The volume occupied by half a mole of a gas at STP is:
    Solution
    The volume occupied by 1 mole of any gas is 22.4 litres.

    So the volume occupied by half a mole of gas would be half of 22.4 litres.

    So it will be $$11.2\ litres$$.

    Hence, option B is correct.
  • Question 3
    1 / -0
    Ethane burning in oxygen to give carbon dioxide and steam. The volume ratio of reactants to products is ______________.
    Solution
    The equation for the combustion reaction of ethane can be written as :
    $$2C_{2}H_{6} + 7O_{2} \rightarrow 4CO_{2} + 6H_{2}O$$
    Therefore the volume ratio of reactants and products $$= 2 : 7 : 4 : 6$$
  • Question 4
    1 / -0
    What is the mass of one atom of $$C-12$$ in grams?
    Solution
    Mass of $$1$$ mole = $$12\,gm$$

    Mass of $$6.022 \times 10^{23}\,atom = 12\,gm$$

    mass of $$1$$ atom = $$\dfrac{12}{6.023 \times 10^{23}} = 1.993 \times 10^{-23}\,gm$$
  • Question 5
    1 / -0
    A neutral atom of an element has a nucleus with a nuclear charge 13 times and mass 27 times that of hydrogen nucleus. What is the ratio of electrons to protons in its stable positively charged ion?
    Solution
    Let the neutral atom of the element be $$X$$.

    Given, the nuclear charge of $$X$$ is 13 times that of the hydrogen nucleus.
    $$\Rightarrow$$ Atomic number $$=13$$

    Mass of X is 27 times that of hydrogen nucleus $$\Rightarrow $$ Mass number $$=27$$.

    Since $$_{13}X^{27}, EC=2, 8, 3$$

    If X forms stable positively charged ion i.e., $$X^{+3}$$ (as it has 3 valence electrons in its valence shell)

    $$X^{+3}\rightarrow$$ Atomic number $$=13-3=10.$$ This implies number of electrons $$=10$$. Number of protons $$=13$$.

    $$Ratio=10 : 13$$ 
  • Question 6
    1 / -0
    Barium chloride reacts with sodium sulphate to form Barium sulphate and sodium chloride. Then, according to the law of conservation of mass:
    Solution
    The law of conservation of mass states that mass can neither be created nor be destroyed, it can only change from one form to the other.
    So, according to the law, the amount of reactants consumed should be equal to the amount of the products formed. 
    Hence option C is correct.
  • Question 7
    1 / -0
    Which law states that the total mass of the reactants is equal to the total mass of the products in a chemical reaction?
    Solution
    Law of conservation of mass states that in a chemical reaction, the total mass of the product is equal to the total mass of the reactants.

    For example
    $$CaCO_3\rightarrow CaO+CO_2$$

    The total mass of reactant $$CaCO_3$$
    $$=40+12+(16\times 3)=100$$

    The mass of $$CaO=40+16=56$$

    Mass of $$CO_2=12+(16\times 2)=44$$

    The total mass of products $$CaO+CO_2=56+44=100$$.

    Hence the above example illustrates that the total mass of reactants $$=$$ total mass of products.
  • Question 8
    1 / -0
    One a.m.u. or one 'u' is equal to :
    Solution
    One a.m.u.(atomic mass unit) or one 'u' is $$\dfrac{1}{12}$$ of the mass of one carbon-$$12$$ atom. 
    It is equal $$1.6605389210 \times 10^{-24} g $$  or $$1.6605389210  \times 10^{-27} kg$$.
  • Question 9
    1 / -0
    The modern atomic mass unit is based on the mass of :
    Solution
    One a.m.u. or one 'u' is equal to $$1.66053892  10^{-24}\ g $$  or $$1.66053892  10^{-27}\ kg$$. It is equal to $$\dfrac{1}{12}$$ of the mass of an atom of carbon-12.

    It is used as a standard. The masses of all other atoms are determined relative to the mass of an atom of carbon-12.
  • Question 10
    1 / -0
    If the fertilizers listed below are priced according to their nitrogen content, which will be the least expensive per $$50$$ kg bag?
    Solution
    Compound                                         %N
    Urea $$(NH_2)_2CO$$                       $$ 28\times\: \dfrac{100}{60} = 46.67%$$

    Ammonia $$NH_3$$                            $$ 14\times \dfrac{100}{17} = 82.35% $$
     
    Ammonium nitrate $$NH_4NO_3        $$     $$  28\times {100}{80} = 35% $$ 

    Guanidine $$HNC(NH_2)_2$$            $$ 42\times {100}{59} = 71.18% $$ 
    Hence, the least expensive will be Ammonium nitrate $$NH_4NO_3$$.
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