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States of Matter Test - 68

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States of Matter Test - 68
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  • Question 1
    1 / -0
    18 g of glucose $${ (C }_{ 6 }{ H }_{ 12 }{ O }_{ 6 })$$ is added to 178.2 g of water. The vapour pressure of water for this aqueous solution at $${ 100 }^{ \circ  }C$$ is ?
    Solution

  • Question 2
    1 / -0
    Gay Lussac's law is not valid for which chemical reaction?
  • Question 3
    1 / -0
    A mixture of 50.ml of $$N{H_3}$$ and 60.0 ml of $${O_2}$$ gas react as
    $$4N{H_3}(g) + 5{O_2}(g)\xrightarrow{{}}4NO + 6{H_2}O(g)$$
    If all the gases are at the same temperature and the reaction continues until one of the gases is completely consumed, what volume of water vapour is produced?
    Solution

  • Question 4
    1 / -0
    The equilibrium constant for the following equilibrium is given at $$0^0C$$:

    $$Na_2HPO_4.12H_2O(s)\rightarrow Na_2HPO_4.7H_2O(s)+5H_2O(g); K_p=31.25 \times 10^{-13}$$. 

    The vapor pressure of water is:
  • Question 5
    1 / -0
    Calculate the mass of a non - volatile solute (molar  mass $$40\,\,g mol^{-1}$$) which should be dissolved in $$114g$$ octane to reduce its vapour pressure to $$80\%$$
    Solution

  • Question 6
    1 / -0
    At $${40^ \circ }C$$ the vapour pressure ( in torr ) of a mixture of methyl alcohol and ethyl alcohol is represented by $$P = 199x + 135$$
    (where $$x$$ is the mole fraction of methyl alcohol) 
    What are the vapour pressures of pure methyl alcohol and pure ethyl alcohol at $${40^ \circ }C$$ ?
    Solution
    Correct option is D

  • Question 7
    1 / -0
    Calculate the vapour pressure of aqueous 0.1 m glucose solution at 300 K temperature, the vapour pressure of water is 0.03 bar at 300 K temperature.
    Solution

  • Question 8
    1 / -0
    $$5.0\ L$$ water placed in a closed room of volume $$2.5\times 10^{4}L$$ having temperature $$300\ K$$. If vapour pressure of water is $$27.0\ mm$$ and density is $$0.990\ g/cm^{3}$$ at this temperature, how much water is left in liquid state?  
  • Question 9
    1 / -0
    At a certain temperature pure liquid A and liquid B have vapour pressures 10 torr and 37 torr respectively. For a certain ideal solution of A and B, the vapour in equilibrium with the liquid has the components A and B in the partial pressure ratio $$P_A : P_B=1 : 7 $$. What is the mole fraction of A in the solution? 
    Solution

  • Question 10
    1 / -0
    When the pressure on a gas is decreased to $$1/4$$ and the absolute temperature is increased four-fold the volume of the gas is:
    Solution

    Hint: The gas which obeys all gas laws is called the ideal gas

    Explanation:
    Ideal gas law is

    $$PV=nRT$$
    Rearranging equation we get;

    $$V = \dfrac{{nRT}}{P}$$

    Where $$P, V $$ are respectively pressure and volume of the gas.

    $$n$$ is the number of moles

    $$T$$ is the temperature of the gas.

    $$R$$ is ridberg constant.

    The pressure on a gas is decreased to $$\dfrac{1}{4}$$ and the absolute temperature is increased four-fold then the volume of the gas is-

    Let, $$P_1, V_1$$ and $$T_1$$ be the pressure, volume, and temperature of the initial stage and $$P_2, V_2$$ and $$T_2$$ be the pressure, volume, and temperature of the final stage.
    Given that;

    $$P_1=\dfrac{P_2}{4} $$ $$- - (i)$$
    $$ P_2 = 4 \times P_1$$

    $$T_1=4T_2$$ $$ - - (ii)$$
    $$ \dfrac {P_1V_1}{T_1} = \dfrac {P_2V_2} {T_2}$$  - ( From Ideal gas as $$n$$ and $$R$$ are constant )
    Putting values of $$P_2$$ and $$T_1$$ $$(i)$$ and $$(ii)$$ in above equation we get;
    $$ \dfrac {P_1V_1}{4T_2} = \dfrac {4P_1V_2} {T_2}$$ 

    Rearranging equation we get;
    $$V_1 = 16 V_2$$

    So, volume will increase $$16$$ times.

    Final Step: Correct option (A).

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