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Thermodynamics ...

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  • Question 1
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    The internal energy of a piece of lead when beaten by a hammer will

  • Question 2
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    6.80 g of $$NH_3$$; is passed over heated CuO. The standard heat enthalpies of $$NH_{3}$$, $$CuO(s)$$ and $$H_2O(l)$$ are -46.0, -155.0 and $$-285 0 \: kJ \: mol^{-1}$$ respectively and the change is.
    $$NH_3 +(3/2)CuO\longrightarrow \frac{1}{2}N_2(g)+ (3/2)H_2O(l) +(3/2)Cu(s)$$.
    If the enthalpy change is 

  • Question 3
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    The enthalpy change for the reaction is:
                       $$XeF_4\longrightarrow Xe^+ +  F^- + F_2 + F; \:  \ \ \ \ \Delta H=?$$


    The average $$Xe-\! \! \! -F$$ bond energy is $$34 \:kcal \:mol^{-1}$$ . $${IE}_1$$ of Xe is $$279 \: kcal \: mol^{-1}$$ and electron affinity of F is $$85 \:kcal \:mol^{-1}$$ and $$e_{F-\! \! \! -F} = 38 \:kcal \: mol^{-1}$$.

  • Question 4
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    The heat capacities of the following gases at room temperature are such that :

  • Question 5
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    The heat required to raise the temperature of a body by 1 K is called :

  • Question 6
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    For the change, $$C_{diamond}\longrightarrow +C_{graphite}; \:\Delta H=-1.89 \:kJ$$, if 6 g of diamond and 6 g of graphite are separately burnt to yield $$CO_2$$ the heat liberated in first case is:

  • Question 7
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    According to law of conservation of energy, the energy can neither be _______ nor _________ .

  • Question 8
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    For the reaction,
          $$C+ O_2\longrightarrow CO_2; \:      \Delta H=-393\:J$$
     $$2Zn + O_2\longrightarrow 2ZnO;\:    \Delta H=-412J\:J$$

    Which one is correct?

  • Question 9
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    Hess's law is related to:

  • Question 10
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    Which one of the following correctly represents the physical significance of Gibb's energy change?

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