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Thermodynamics ...

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  • Question 1
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    The heats of combustion of rhombic and monoclinic sulphur are $$-70960$$ and $$-71030$$ calorie respectively. What will be the heat of conversion of rhombic sulphur to monoclinic sulphur?

  • Question 2
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    The heats of combustion of yellow phosphorus and red phosphorus are $$-9.91kJ$$ and $$-8.78kJ$$ respectively. The heat of transition of yellow phosphorus to red phosphorus is:

  • Question 3
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    For an exothermic reaction to be spontaneous:

  • Question 4
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    For which reaction from the following, $$\Delta S$$ will be maximum?

  • Question 5
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    On combustion carbon forms two oxides $$CO$$ and $${CO}_{2}$$, heat of formation of $${CO}_{2}$$ is $$-94.3\ kcal$$ and that of $$CO$$ is $$-26.0 \ kcal$$. Heat of combustion of carbon is:

  • Question 6
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    The heat of combustion of ethanol determined in a bomb calorimeter is $$-670.48kcal$$ $${mol}^{-1}$$ at $$298K$$. What is the $$\Delta U$$ at $$298K$$ for the reaction?

  • Question 7
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    $$\Delta { G }^{ o }$$ for the reaction $$x+y\rightleftharpoons z$$ is $$-4.606kcal$$. The value of equilibrium constant of the reaction at $${227}^{o}C$$ is:
    ($$R=2.0cal.{mol}^{-1}{K}^{-1}$$)

  • Question 8
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    Considering entropy(s) as a thermodynamic parameter, the criterion for the spontaneity of any process is:

  • Question 9
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    Calculate $$\triangle G^{\circ}$$ for the following cell reaction:

    $$Zn(s) + Ag_{2}O(s) + H_{2}O(l) \rightleftharpoons Zn^{2+}(aq) + 2Ag(s) + 2OH^{-}(aq)$$

    $$E^{\circ}_{Ag^{+}/Ag} = + 0.80V$$ and $$E^{\circ}_{Zn^{2+}/ ZN} = -0.76V$$.

  • Question 10
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    Which of the following is true for spontaneous process?

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