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Thermodynamics ...

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  • Question 1
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    For the reaction of one mole zinc dust with one mole sulphuric acid in a bomb calorimeter, $$\triangle U$$ and w correspond to?

  • Question 2
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    For $$ { Zn }^{ 2+ }/Zn $$ ,
    $$ { E }^{ \circ  }=-0.76\quad V $$,
    for $$ { Ag }^{ + }/Ag\quad { E }^{ \circ  }=\quad 0.799\quad V $$.
    The correct statement is:

  • Question 3
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    Suppose that a reaction has $$\Delta H=40\ kJ$$ and $$\Delta S=50\ kJ/ K$$. At what temperature range will it change from spontaneous to non-spontaneous?

  • Question 4
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    Two liquids are at $$40^oC$$  and $$30^oC.$$ When they are mixed in equal masses , the temperature of the mixture is $$36^oC.$$ Ratio of their specific heats is 

  • Question 5
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    The value closest to the thermal velocity of a Helium atom at room temperature (300 K) in $$ms^{-1}$$ is : [$$k_B = 1.4 \times 10^{-23} \ J/K ; \ m_{He} = 7\times 10^{-27} \ kg$$ ]

  • Question 6
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    For the reaction; $${ FeCO }_{ 3(s) }\longrightarrow { Fe }O_{ (s) }+C{ O }_{ 2 }(g)$$, $$\Delta H=82.8\ kJ$$ at $${ 25 }^{ 0 }C$$. What is $$\Delta U$$ at $${ 25 }^{ 0 }C$$?

  • Question 7
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    For a reaction to occur spontaneously:

  • Question 8
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    $$\Delta S $$ for $$4Fe_(s)+3O_{2(g)}\rightarrow 2Fe_2O_{3(s)}$$ is $$550J/mol/K$$. The process is found to be spontaneous even at $$298K$$ $$[\Delta H=-1650kJ]$$

  • Question 9
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    The incorrect criterion for the spontaneity of a process is:

  • Question 10
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    $$0.1 \,{m^3}$$ of water at $${80^ \circ }$$ is mixed with $$0.3 {m^3}$$ of water at $${60^ \circ }$$. The final temperature of mixture is :

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