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Thermodynamics ...

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  • Question 1
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    $$C(s) + O_2(g) \to CO_2(g); \quad \Delta H = -94kcal$$

    $$2CO(g) + O_2(g) \to 2CO_2(g); \quad \Delta H = -135.2 kcal$$

    The heat of formation of $$CO(g)$$ is :

  • Question 2
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    Suppose that a reaction has $$\Delta H=-40kJ$$ and $$\Delta S=-50J/K$$. At what temperature range will it change from spontaneous to non-spontaneous ?

  • Question 3
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    Consider the reaction, $$2A_{(g)} + B_(g) rightleftarrow 2C_{(g)}$$ for which $$K_c = 350$$. If $$0.01$$ mole of each of the reactants and product are mixed in a $$2.0$$L flask, then the reaction quotient and the spontaneous direction of the system will be?

  • Question 4
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    $$\Delta H$$ and $$\Delta S$$ are $$-283\ kJ$$ and $$-87\ J\ K^{-1}$$, respectively. It was intended to carry out this reaction at $$1000, 1500, 3000$$ and $$3500\ K$$. At which of these temperatures would this reaction be thermodynamically spontaneous?

  • Question 5
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    Which of the following statements is wrong?

  • Question 6
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    Which of the following is not true about a reversible reaction?

  • Question 7
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    $$2{H}_{2(g)}+{O}_{2(g)}\rightarrow 2{H}_{2}{O}_{(l)};\Delta H=-ve$$ and $$\Delta G=-ve$$. Then the reaction is

  • Question 8
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    Which of the following expression for an irreversible process:

  • Question 9
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    In standard state the non spontaneous reaction among the following is:

  • Question 10
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    Answer the question based on the diagram involving $$1$$ mole of ideal gas.
    Process $$A\rightarrow B$$ represents:

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