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Thermodynamics ...

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  • Question 1
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    Which of the following can be calculated from Born-Haber cycle for $$Al_2O_3$$?

  • Question 2
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    A constant volume gas thermometer shows pressure reading of 50 cm and 90 cm of mercury at 0$$^{0}C$$ and 100$$^{0}C$$ respectively. When the pressure reading is 60 cm  of mercury, the temperature is:-

  • Question 3
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    A vessel contains $$N$$ molecules of a gas at temperature $$T$$. Now the number of molecules is doubled, keeping the total energy in the vessel constant. The temperature of the gas is.

  • Question 4
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    If the temperature difference $$T_1 - T_2$$ is $$120^oC$$. the temperature difference between points A & B is 

  • Question 5
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    When 250 KJ heat is the system then it does work of 400 KJ then calculate change in internal energy of system ?

  • Question 6
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    1 g of a steam at $$100^{_-^0}C$$ melt how much ice at $$0^{_-^0}C$$? (Latent heat of ice = 80 cal/gm and latent heat of steam = 540 cal/gm)-

  • Question 7
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    One gram of ice (at $$0^{o}C$$) is mixed with one gram of steam (at $$100^{o}C$$). After thermal equilibrium, the temperature of the mixture is

  • Question 8
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    Internal energy of an ideal gas depends on:

  • Question 9
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    Calculate $${ \Delta  }_{ r }G$$ for the reaction at $$2\mathring { 7\quad  } C$$ :-
    $${ H }_{ 2(g) }+2A{ g }_{ (aq) }^{ + }\rightleftharpoons 2A{ g }_{ s }+2{ H }_{ (aq)}^{+} $$
    Given : $${ P }_{ { H }_{ 2 } }=0.5$$ bar; $${ [A{ g }^{ + }] }=1{ 0 }^{ -5 }M$$ 
    $${ [{ H }^{ + }] }=1{ 0 }^{ -3 }M$$ ; 
    $${ \triangle  }_{ r }\mathring { G\quad \quad  } [A{ g }^{ + }]=77.1\quad KJ/mol$$

  • Question 10
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    What is the change in entropy when $$2.5 $$ mole of water is heated from $$27^{o}C$$ to $$87^{o}C$$? Assume that the heat capacity is constant $$(C_{p.m}(H_{2}O)=4.2\ J/g-K\ In (1.2)=0.18)$$

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