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Thermodynamics ...

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  • Question 1
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    The favourable conditions for a spontaneous reaction are:

  • Question 2
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    Which of the following conditions make the process non spontaneous at all temperatures. 

  • Question 3
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    Two samples of DNA, A and B have melting points $$340K$$ and $$350K$$ respectively. This is because

  • Question 4
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    Which of the following statements/relationships is not correct in thermodynamic changes?

  • Question 5
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    For a spontaneous reaction, the $$\Delta G$$, equilibrium constant, $$K$$ and will be respectively:

  • Question 6
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    Assuming that water vapour is an ideal gas, the internal energy change ($$\Delta U$$) when $$1mol$$ of water is vaporised at $$1$$ bar pressure and $${100}^{o}C$$ will be:

    (Given: Molar enthalpy of vapourisation of water at $$1$$ bar and $$373K=41\ kJ.{mol}^{-1}$$ and $$R=8.3J{mol}^{-1}$$ $${K}^{-1}$$)

  • Question 7
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    $$\Delta {G}^{o}$$ of $${Cu}_{(aq)}^{+}$$ and $${Cu}_{(aq)}^{2+}$$ respectively are $$+50$$ and $$+66kJ/mole$$. Value of ($$\Delta{H}^{o}-T\Delta {S}^{o}$$) for $${Cu}_{(aq)}^{+}\rightarrow {Cu}_{(aq)}^{2+}$$ in kilo joules is?

  • Question 8
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    For a gaseous reaction,
    $$A(g)+3B(g)\rightarrow 3C(g)+3D(g)$$


    $$\Delta E$$ is $$17kcal$$ at $${27}^{o}C$$, assuming $$R=2cal$$ $${K}^{-1}$$ $${mol}^{-1}$$, the value of $$\Delta H$$ for the above reaction is:

  • Question 9
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    $$\Delta{S}_{surroundings}=+959.1J{K}^{-1}{mol}^{-1}$$
    $$\Delta{S}_{system}=-163.1J{K}^{-1}{mol}^{-1}$$. Then process is?

  • Question 10
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    For the spontaneous process $$2F(g)\rightarrow {F}_{2}(g)$$, the sign of $$\Delta H$$ and $$\Delta S$$ respectively are?

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